We report an experimental study of phase synchronization in a pair of interacting nuclear spins subjected to an external drive in nuclear magnetic resonance architecture. A weak transition-selective radio-frequency field applied on one of the spins is observed to cause phase localization, which is experimentally established by measuring the Husimi distribution function under various drive conditions. To this end, we have developed a general interferometric technique to directly extract values of the Husimi function via the transverse magnetization of the undriven nuclear spin. We further verify the robustness of synchronization to detuning in the system by studying the Arnold tongue behavior.

We explore the dynamics of $N$ coupled atomic two-level systems embedded within a generic bosonic reservoir under specific system symmetries. In the regime of many atoms identically coupled to a single reservoir, we identify remarkable effects, notably that the initial configuration of the atomic excited-state amplitudes strongly impacts the dynamics of the system and can even fully sever the system from its environment. Additionally, we find that steady-state amplitudes of the excited states become independent of the specific structure of the bosonic reservoirs considered. The framework introduced is deployed to model a structured photonic reservoir associated with a photonic crystal, where it recaptures previous theoretical and experimental results for the superradiance rates even within the single-excitation regime. For the photonic band-gap system, our formalism predicts the generation of pairwise entanglement between initially uncorrelated atomic systems. Furthermore, it suggests that—with respect to a non-Markovian metric—the non-Markovianity of the aggregated many-atom system is modulated by the total number of atoms. This is due to a stark interplay between the Lamb shifting of the atomic transition energies due to their varying number and the increased number of atomic systems with resonant transition energies.

A direct measurement protocol allows reconstructing specific elements of the density matrix of a quantum state without using quantum state tomography. Until now, most direct measurement protocols have relied on ancillary pointers, which add complexity and are not always easy to implement experimentally. In this paper, we experimentally validate a direct measurement protocol requiring no ancillary pointers that calculates the value of a specific element of a quantum state's density matrix using only six projection measurements. We prepare path-encoded arbitrary four-dimensional quantum states on a silicon-based quantum photonic chip and measure the density-matrix elements of the four-dimensional quantum states using this protocol, with experimental results deviating from ideal values by an average of only $0.010\pm 0.004$. This approach has the potential to be applied to quantum information applications where only partial information about the quantum state needs to be extracted, for example, problems such as entanglement witnessing, fidelity estimation of quantum systems, and quantum coherence estimation.

The Larmor time of an incident wave packet has recently been measured experimentally [R. Ramos, D. Spierings, I. Racicot, and A. M. Steinberg, Nature (London) 583, 529 (2020)]. It differs essentially from previous well-studied free-particle cases, whereas the unique properties of wave packets are unrevealed in their theoretical analysis and state-of-the-art Larmor clock studies. In this paper, we study the Larmor time of a bound two-component electron wave packet and supplement the theoretical lack of wave-packet tunneling. We find that the spin shows a pure Larmor precession in the plane perpendicular to the field without a rotation parallel to the field. The Larmor time is defined in the limit of vanishing field where the precession angle is proportional to the field. For relatively weak fields, this precession angle will respond to the field approximately linearly. For the wave-packet tunneling case, we propose an effective scheme that utilizes the fidelity of the tunneled wave packets to calibrate an approximate linear-response region. Furthermore, we show that in the approximate linear-response region the change in the fidelity can be approximately regarded as the result of the accumulated displacement in phase space. This result reveals the inner mechanism of wave-packet tunneling. Our findings may have implications for future experiments of the Larmor clock.

We investigate numerically a one-dimensional Bose-Einstein condensate illuminated by off-resonant laser light which is retroreflected by a single feedback mirror. Studying the ground states of the system, we find density structures which are self-trapped via the optomechanical action of the diffracted light. We show that these structures are stable and exhibit Newtonian dynamics. We propose that these results allow continuous, nondestructive monitoring of condensate dynamics via the optical intensity and may offer opportunities for optical control and transport of coherent matter via gradients in optical phase alone.

The hierarchy of nonlocality and entanglement in multipartite systems is one of the fundamental problems in quantum physics. We study this topic in three-qubit systems considering the entanglement classification of stochastic local operations and classical communication (SLOCC). The equivalence under SLOCC divides three-qubit states into separable, biseparable, $W$, and Greenberger-Horne-Zeilinger (GHZ) classes. The $W$ and GHZ are two subclasses of genuine tripartite entanglement. We adopt the family of GHZ-symmetric states as a research subject, which share the symmetries of the GHZ state and have a complete characterization of SLOCC classes. In the biseparable region (with bipartite entanglement), there exist GHZ-symmetric states that are found to be fully local. In addition, there are bilocal states in both the $W$ and GHZ classes. That is, neither of the subclasses of genuine tripartite entanglement can ensure genuinely tripartite nonlocality.

We consider the dissipative charging process of quantum batteries in terms of a collisional model, where the batteries are coupled to a heat bath using nonenergy preserving interactions. First, we show that for low temperatures, the collective process can attain a charging power that increases polynomially with the number of batteries. The scaling we find is $N^3$ which, while being greater than the bound obtained for unitary processes, has a lower efficiency. Then, we study the dissipative charging process of a single battery using a time-dependent Hamiltonian that generates coherences in the energy basis. In this case, we find that the presence of coherence could enhance the charging power and also its efficiency. Finally, we show how this process can be used in a quantum heat engine that contains the charging process as one of its open strokes.

The continuous-time differential Lyapunov equation is widely used in linear optimal control theory, a branch of mathematics and engineering. In quantum physics, it is known to appear in Markovian descriptions of linear (quadratic Hamiltonian, linear equations of motion) open quantum systems, typically from quantum master equations. Despite this, the Lyapunov equation is seldom considered a fundamental formalism for linear open quantum systems. In this work we aim to change that. We establish the Lyapunov equation as a fundamental and efficient formalism for linear open quantum systems that can go beyond the limitations of various standard quantum master-equation descriptions, while remaining of much less complexity than general exact formalisms. This also provides valuable insights for non-Hermitian quantum physics. In particular, we derive the Lyapunov equation for the most general number-conserving linear system in a lattice of arbitrary dimension and geometry, connected to an arbitrary number of baths at different temperatures and chemical potentials. Three slightly different forms of the Lyapunov equation are derived via an equation-of-motion approach, by making increasing levels of controlled approximations, without reference to any quantum master equation. Then we discuss their relation with quantum master equations, positivity, accuracy, and additivity issues, the possibility of describing dark states, general perturbative solutions in terms of single-particle eigenvectors and eigenvalues of the system, and quantum regression formulas. Our derivation gives a clear understanding of the origin of the non-Hermitian Hamiltonian describing the dynamics and separates it from the effects of quantum and thermal fluctuations. Many of these results would have been hard to obtain via standard quantum master-equation approaches.

Variational quantum algorithms (VQAs) are increasingly being applied in simulations of strongly bound (covalently bonded) systems using full molecular orbital basis representations. The application of quantum computers to the weakly bound intermolecular and noncovalently bonded regime, however, has remained largely unexplored. In this work, we develop a coarse-grained representation of the electronic response that is ideally suited for determining the ground state of weakly interacting molecules using a VQA. We require qubit numbers that grow linearly with the number of molecules and derive scaling behavior for the number of circuits and measurements required, which compare favorably to traditional variational quantum eigensolver methods. We demonstrate our method on IBM superconducting quantum processors and show its capability to resolve the dispersion energy as a function of separation for a pair of nonpolar molecules—thereby establishing a means by which quantum computers can model Van der Waals interactions directly from zero-point quantum fluctuations. Within this coarse-grained approximation, we conclude that current-generation quantum hardware is capable of probing energies in this weakly bound but nevertheless chemically ubiquitous and biologically important regime. Finally, we perform experiments on simulated and real quantum computers for systems of three, four, and five oscillators as well as oscillators with anharmonic onsite binding potentials; the consequences of the latter are unexamined in large systems using classical computational methods but can be incorporated here with low computational overhead.

Quantum collision models are receiving increasing attention as they describe many nontrivial phenomena in the dynamics of open quantum systems. In a general scenario of both fundamental and practical interest, a quantum system repeatedly interacts with individual particles or modes, forming a correlated and structured reservoir; however, classical and quantum environment correlations greatly complicate the calculation and interpretation of the system dynamics. Here, we propose an exact solution to this problem based on the tensor network formalism. We find a natural Markovian embedding for the system dynamics, where the role of an auxiliary system is played by virtual indices of the network. The constructed embedding is amenable to an analytical treatment for a number of timely problems such as the system interaction with two-photon wave packets, structured photonic states, and one-dimensional spin chains. We also derive a time-convolution master equation and relate its memory kernel with the environment correlation function, thus revealing a clear physical picture of memory effects in the dynamics. The results advance tensor-network methods in the fields of quantum optics and quantum transport.

We address multiparameter quantum estimation for one-dimensional discrete-time quantum walks and its applications to quantum metrology. We use the quantum walker as a probe for the unknown parameters encoded in its coin degrees of freedom. We find an analytic expression of the quantum Fisher information matrix for the most general coin operator, and show that only two out of the three coin parameters can be accessed. We also prove that the resulting two-parameter coin model is asymptotically classical, i.e., the Uhlmann curvature vanishes. Finally, we apply our findings to relevant case studies, including the simultaneous estimation of charge and mass in the discretized Dirac model.

We obtain a classical analog of the quantum covariance matrix by performing its classical approximation for any continuous quantum state, and we illustrate this approach with the anharmonic oscillator. Using this classical covariance matrix, we propose classical analogs of the purity, linear quantum entropy, and von Neumann entropy for classical integrable systems, when the quantum counterpart of the system under consideration is in a Gaussian state. As is well known, this matrix completely characterizes the purity, linear quantum entropy, and von Neumann entropy for Gaussian states. These classical analogs can be interpreted as quantities that reveal how much information from the complete system remains in the considered subsystem. To illustrate our approach, we calculate these classical analogs for three coupled harmonic oscillators and two linearly coupled oscillators. We find that they exactly reproduce the results of their quantum counterparts. In this sense, it is remarkable that we can calculate these quantities from the classical viewpoint.

We investigate the scenario where an observer, Alice, shares a two-qubit state with an arbitrary number of observers, Bobs, via sequentially and independently recycling the qubit in possession of the first Bob. It is known that there exist entangled states which can be used to have an arbitrarily long sequence of Bobs who can violate the Clauser-Horne-Shimony-Holt (CHSH) Bell inequality with the single Alice. We show that there exist entangled states that do not violate the Bell inequality and whose entanglement can be detected by an arbitrary number of Bobs by suitably choosing the entanglement witness operator and the unsharp measurement settings by the Bobs. This proves that the set of states that can be used to witness entanglement sequentially is larger than those that can witness sequential violation of local realism. There exist, therefore, two-party quantum correlations that are Bell “classical”, but whose entanglement “nonclassicality” can be witnessed sequentially and independently by an arbitrarily large number of observers at one end of the shared state with the single observer at the other end.

We obtain the superfluid transition temperature of equal Rashba-Dresselhaus spin-orbit- and Rabi-coupled Fermi superfluids, from the Bardeen-Cooper-Schrieffer (BCS) to Bose-Einstein condensate (BEC) regimes in three dimensions for tunable $s$-wave interactions. In the presence of Rabi coupling, we find that spin-orbit coupling enhances (reduces) the critical temperature in the BEC (BCS) limit. For fixed interactions, we show that spin-orbit coupling can convert a first-order (discontinuous) phase transition into a second-order (continuous) phase transition, as a function of Rabi coupling. We derive the Ginzburg-Landau free energy to sixth power in the superfluid order parameter to describe both continuous and discontinuous phase transitions as a function of spin-orbit and Rabi couplings. Lastly, we develop a time-dependent Ginzburg-Landau fluctuation theory for an arbitrary mixture of Rashba and Dresselhaus spin-orbit couplings at any interaction strength.

An analysis is given for the Fabry-Perot cavity having a combination of dissipative and dispersive optomechanical coupling. It is established that the combined coupling leads to optical rigidity. At the same time, this rigidity appears in systems with the combined coupling on the resonant pump, which is not typical for pure dispersive and dissipative couplings. A proposal is made to use this system to detect small signal forces with better sensitivity than the standard quantum limit. It is also demonstrated that this optomechanical system can create ponderomotive squeezing with controllable parameters over a wider range than ponderomotive squeezing using dispersive coupling.

Nanostructures in the form of ellipsoids, prolate spheroids, rings, and cylinders are known to exhibit resonant surface and cavity modes with applications in nanophotonics and plasmonics and, more recently, in novel quantum experiments, in which control of plasmons and their interactions with plasmons, photons, phonons, excitons, and quantum emitters are desired. Nanorods and nanowires are examples of plasmonic structures with spectral properties of potential use as interconnects and circuit components. Estimates of the surface properties of these components are needed in circuit design and integrated systems. Here, we present a quantum Hamiltonian for the cylindrical surface charge density. We then study the photon excitation of plasmons on the cylindrical surface and calculate their scattering and radiative decay rate. Nonradiative decay of plasmons induces an efficient heating of the nanoparticle and can photoacoustically excite mechanical oscillations. Computational calculations are also presented for the plasmonic modes and the ensuing excitations of nanomechanical eigenmodes of nanoparticles with near-cylindrical symmetries.

The cascade-emitted biphotons generated from alkali metal atomic ensembles are an excellent entanglement resource which enables long-distance quantum communication. The communication of quantum information between distant locations can be realized by utilizing the low-loss telecom bandwidth in the upper transition of the cascaded photons in a fiber-based quantum network. Meanwhile, the infrared photon from the lower transition of this highly directional and frequency-correlated biphoton can be created using the four-wave mixing process and can be stored locally as a collective spin wave. Here, we theoretically investigate the frequency entanglement of this biphoton and propose two approaches to remove the two photons' mutual correlations in frequency spaces. The first approach applies an optical cavity which modulates the biphoton spectrum into a more symmetric and narrow spectral function by multiplexing multiple atomic ensembles with phase compensation. The purity of the single photons reaches up to 0.999, and the entanglement entropy $S$ of the biphoton is reduced to 0.006, which is 200 times smaller than the one without multiplexing. The other approach employs a symmetric pumping of the laser fields in two atomic ensembles, which leads to a moderate reduction of $S\sim 0.3$ when nondiscrimination detection devices are used for both photons. An extremely low frequency entanglement implies an almost indistinguishable single-photon source, which offers a potential resource for photonic quantum emulation and computation.

We show that the light generated via spontaneous four-wave mixing or parametric down conversion in multiple, coupled, lossy cavities is a multimode squeezed thermal state. Requiring this state to be the solution of the Lindblad master equation results in a set of coupled first-order differential equations for the time-dependent squeezing parameters and thermal photon numbers of the state. The benefit of this semianalytic approach is that the number of coupled equations scales linearly with the number of modes and is independent of the number of photons generated. With this analytic form of the state, correlation variances are easily expressed as analytic functions of the time-dependent mode parameters. Thus, our solution makes it computationally tractable and relatively straightforward to calculate the generation and evolution of multimode entangled states in multiple coupled, lossy cavities, even when there are a large number of modes and/or photons.

Quantum computing and machine learning have potential for symbiosis. However, in addition to the hardware limitations from current devices, there are still basic issues that must be addressed before quantum circuits can usefully incorporate with current machine learning tasks. We report a strategy for such an integration in the context of attention models used for reinforcement learning. Agents that implement attention mechanisms have successfully been applied to certain cases of combinatorial routing problems by first encoding nodes on a graph and then sequentially decoding nodes until a route is selected. We demonstrate that simple quantum circuits can be used in place of classical attention head layers while maintaining performance. Our method modifies attention mechanisms by replacing key and query vectors for every node with quantum states that are entangled before being measured. The resulting hybrid classical-quantum agent is tested in the context of vehicle routing problems where its performance is competitive with the original classical approach. We regard our model as a prototype that can be scaled up and as an avenue for further study on the role of quantum computing in reinforcement learning.