The quantum relative entropy is known to play a key role in determining the asymptotic convertibility of quantum states in general resource-theoretic settings, often constituting the unique monotone that is relevant in the asymptotic regime. We show that this is no longer the case when one allows stochastic protocols that may only succeed with some probability, in which case the quantum relative entropy is insufficient to characterize the rates of asymptotic state transformations, and a new entropic quantity based on a regularization of the Hilbert projective metric comes into play. Such a scenario is motivated by a setting where the cost associated with transformations of quantum states, typically taken to be the number of copies of a given state, is instead identified with the size of the quantum memory needed to realize the protocol. Our approach allows for constructing transformation protocols that achieve strictly higher rates than those imposed by the relative entropy. Focusing on the task of resource distillation, we give broadly applicable strong converse bounds on the asymptotic rates of probabilistic distillation protocols, and show them to be tight in relevant settings such as entanglement distillation with nonentangling operations. This generalizes and extends previously known limitations that are only applicable to deterministic protocols. Our methods are based on recent results for probabilistic one-shot transformations as well as a new asymptotic equipartition property for the projective relative entropy.

The weak-value amplification is extensively considered in precision metrology in order to achieve a higher sensitivity. Despite the practical benefits in amplifying small physical quantities, its metrological advantage still arouses a broad debate due to the low postselection probability of success. In this paper, by employing the quantum Fisher information metric, we show that the precision of estimating an unknown parameter can be improved by introducing a precoupling process with properly chosen interaction operators. We point out this result is credible for both real and imaginary weak values. By tracking the meter wave functions, we find this enhancement of estimation precision comes from a precoupling induced modulation of the meter wave function, thus the most sensitive regime with respect to the parameter is reached. In addition, the estimation error is investigated by considering the difference between the theoretical and estimated value. The analysis suggests that this kind of error can be effectively suppressed by averaging the estimations resulted from different initial meter states. These results are finally illustrated by an exact numerical simulation where the advantages of our proposal are displayed by the comparison to the standard weak-value amplification scheme.

We report a method for producing ultracold ${\mathrm{HD}}^{+}$ molecular ions populated in a rotational ground state in an ion trap based on $\left[2+1^{\prime }\right]$ resonance-enhanced threshold photoionization (RETPI) and sympathetic cooling with the laser-cooled ${\mathrm{Be}}^{+}$ ions. The effects of electric field of the ion trap on the RETPI process of neutral HD molecules and the blackbody radiation (BBR) on the population evolution of rotational states of the generated polar ${\mathrm{HD}}^{+}$ ions have been studied. The initial rotational-ground-state population of ${\mathrm{HD}}^{+}$ ions is 0.93(12). After the cumulation time of 5 s, the rotational-ground-state population is reduced to 0.77(8) due to the BBR coupling. This method of generating ultracold state-selected ${\mathrm{HD}}^{+}$ ions is beneficial for the studies in precision rovibrational spectroscopy, state-controlled cold chemical reaction, and quantum logic spectroscopy.

We demonstrate the use of an auxiliary microwave field to extend the bandwidth sensitivity of Rydberg-atom-based microwave electrometry. Electromagnetically induced transparency (EIT) and Autler-Townes (AT) splitting in Rydberg atom microwave electrometry provide advantageous sensitivity for the resonant detection of microwave (MW) fields because the Stark shift of the target Rydberg state takes the linear form of AT splitting. However, the sensitivity is reduced by several orders of magnitude for detuned MW fields because the Stark shift of the target Rydberg state depends on a weak nonlinear effect. We show that the auxiliary microwave field with appropriate Rabi frequency or detuning could shift the atomic energy levels to bring a particular Rydberg-Rydberg transition of interest for microwave sensing into resonance with the target microwave field. Using the atomic superheterodyne method, we verified the general method that regulates Rydberg energy levels using an auxiliary microwave field. The experimental results of this study confirm that this technique works efficiently for detecting microwave fields detuned by up to 100 MHz from resonance with the field-free Rydberg-Rydberg transition used for sensing. The measurement sensitivity of the detuned target field is increased by a factor of 10 compared with that achieved without the application of the auxiliary dressing field.

It is argued that the dynamic core-electron polarization (DCEP) in polar molecules primarily affects harmonic processes at the ionization step only. This manifestation can also be understood in view of the strong-field assumption that the parent ion's potential becomes irrelevant when the electron is accelerated in the continuum-energy region. However, the scenario becomes vastly different, especially in the case of long-wavelength lasers as shown in this paper, where we demonstrate a complete physical picture of the DCEP on the harmonic process from asymmetric carbon monoxide (CO) molecules comprising the propagation step. To do so, we develop a visualization method for the harmonic process with and without DCEP based on Bohmian mechanics. As tracer particles evolving along quantum trajectories, Bohmian trajectories provide an intuitive picture of the “harmonic process from the CO molecules. Remarkably, when the change of the harmonic intensity with respect to the DCEP inclusion cannot be explained by the instantaneous ionization rate, the Bohmian trajectories can attribute this change to the difference in the number of returning events and returning time of the electron after the propagation stage. By analyzing the dynamics of individual Bohmian trajectories (the acceleration and the time-frequency profile), we show that the DCEP alters nonlocally the innermost trajectories, which encode all the dynamics of the harmonic process. This insight into the DCEP effect necessitates a careful reinvestigation into other strong-field physics theories on the role of the target over the propagation stage.

A paramagnetic-ferromagnetic quantum phase transition is known to occur at zero temperature in a two-dimensional coherently coupled Bose mixture of dilute ultracold atomic gases provided the interspecies interaction strength is large enough. Here we study the fate of such a transition at finite temperature by performing numerical simulations with the stochastic (projected) Gross-Pitaevskii formalism, which includes both thermal and beyond mean-field effects. By extracting the average magnetization, the magnetic fluctuations and characteristic relaxation frequency (or critical slowing down), we identify a finite-temperature critical line for the transition. We find that the critical point shifts linearly with temperature and, in addition, the three quantities used to probe the transition exhibit a temperature power-law scaling. The scaling of the critical slowing down is found to be consistent with thermal critical exponents and is very well approximated by the square of the spin excitation gap at zero temperature.

Quantum Hall physics is at the heart of research on both matter and artificial systems, such as cold atomic gases, with nontrivial topological order. We report on the observation of a chiral edge current by transferring atomic wave packets simultaneously to opposite edges of a synthetic Hall system realized in the two-dimensional state space formed by one spatial and one synthetic dimension encoded in the $J=6$ electronic spin of erbium atoms. To characterize the system, the Hall drift of the employed atomic Bose-Einstein condensate in the lowest Landau-like level is determined. The topological properties are verified by determining the local Chern marker, and upon performing low-lying excitations both cyclotron and skipping orbits are observed in the bulk and edges, respectively. Future prospects include studies of novel topological phases in cold-atom systems.

The sensitivity of laser interferometers is fundamentally limited by the quantum nature of light. Recent theoretical studies have opened a new avenue to enhance their quantum-limited sensitivity by using active parity-time-symmetric and phase-insensitive quantum amplification. These systems can enhance the signal response without introducing excess noise in the ideal case. However, such active systems must be causal, stable, and carefully tuned to be practical and applicable to precision measurements. In this paper, we show that phase-insensitive amplification in laser interferometers can be implemented in a tabletop experiment. The layout consists of two coupled cavities and an active medium comprised of a silicon nitride membrane and an auxiliary pump field. Our design relies on existing membrane and cryogenic technology and can demonstrate three distinct features: (i) the self-stabilized dynamics of the optical system, (ii) quantum enhancement of its sensitivity in the presence of the amplifier, and (iii) optical control of the amplifier gain. These features are needed to enhance the sensitivity of future interferometric gravitational-wave and axion detectors.

The concept of majorization is explored as a tool to characterize the performance of a quantum Otto engine in the quasistatic regime. For a working substance in the form of a single spin of arbitrary magnitude, majorization yields a necessary and sufficient condition for the operation of the Otto engine, provided the canonical distribution of the working medium at the hot reservoir is majorized by its canonical distribution at the cold reservoir. We extend our analysis for two scenarios: a three-level atom and a bipartite system consisting of spin 1/2 interacting with an arbitrary spin via an isotropic Heisenberg exchange interaction. For both these cases, we find that while a majorization condition implies positive work extraction, it only yields sufficient conditions for the engine operation. Finally, we study the local thermodynamics of spins in the case of the bipartite system and infer an upper bound on the quantum Otto efficiency using the majorization relation.

We calculate the quantum Fisher information (QFI) for estimating, using a circular imaging aperture, the two-dimensional location of a point source against a uniformly bright disk of known center and radius in the ideal photon-counting limit. We present both a perturbative calculation of the QFI in powers of the background-to-source brightness ratio and a numerically exact calculation of the QFI in the eigenbasis of the one-photon density operator. A related problem of the quantum limit on estimating the location of a small-area brightness hole in an otherwise uniformly bright disk, a problem of potential interest to the extrasolar planet detection community, is also treated perturbatively in powers of the ratio of the areas of the hole and the background disk. We then numerically evaluate the Cramér-Rao lower bound (CRB) for wavefront projections in three separate bases, those comprising Zernike, Fourier-Bessel, and localized point-source modes, for unbiased estimation of the two position coordinates of the point source and of the brightness hole center, respectively, for the two problems. By comparing these CRBs with the corresponding quantum-limited minimum error variances, given by inverting the QFI matrix, and with the CRBs associated with direct imaging, we assess the maximum efficiency of these wavefront projections in performing such estimations.

We propose several approaches for solving regression problems and differential equations (DEs) with quantum kernel methods. We compose quantum models as weighted sums of kernel functions, where variables are encoded using feature maps and model derivatives are represented using automatic differentiation of quantum circuits. While previously quantum kernel methods primarily targeted classification tasks, here we consider their applicability to regression tasks, based on available data and differential constraints. We use two strategies to approach these problems. First, we devise a mixed model regression with a trial solution represented by kernel-based functions, which is trained to minimize a loss for specific differential constraints or datasets. Second, we use support vector regression that accounts for the structure of differential equations. The developed methods are capable of solving both linear and nonlinear systems. Contrary to prevailing hybrid variational approaches for parametrized quantum circuits, we perform training of the weights of the model classically. Under certain conditions this corresponds to a convex optimization problem, which can be solved with provable convergence to global optimum of the model. The proposed approaches also favor hardware implementations, as optimization only uses evaluated Gram matrices, but require a quadratic number of function evaluations. We highlight trade-offs when comparing our methods to those based on variational quantum circuits such as the recently proposed differentiable quantum circuits approach. The proposed methods offer potential quantum enhancement through the rich kernel representations using the power of quantum feature maps, and start the quest towards provably trainable quantum DE solvers.

Twin-field quantum key distribution (TF-QKD) and its variants provide a promising solution for sharing information-theoretic secure keys between intercity peers since they are able to overcome the fundamental rate-transmittance bound without quantum repeaters. In this paper, we propose to improve the key rate at long distances and the maximum achievable distance for TF-QKD by deriving the error rates under three mutually unbiased bases, i.e., ${\sigma }_X, {\sigma }_Y$, and ${\sigma }_Z$ in two-dimensional Hilbert space. Moreover, learning these error rates, one can add noisy preprocessing to further improve its performance. We also observe that higher bit error rates do not necessarily imply lower key rates when noisy preprocessing is added. Our method does not change the existing physical implementation or experimental operation, but only requires simple postprocessing of the experimental data, which can be directly used to improve the key rate performance of the existing QKD system. The simulation results demonstrate its notable enhancements in terms of key rate at long distances and the maximum achievable distance for the phase-encoded TF-QKD protocol.

In this paper, we study the optical-hysteresis regime in a driven-dissipative Bose-Hubbard dimer under a symmetric configuration and analyze the classical optical bistability with the Gross-Pitaevskii mean-field approach. We find that the critical point of the optical-hysteresis regime can be determined by the classical optical-bistability transformation predicted with a steady state equation, and the critical tunneling rate is given by analyzing the bistable threshold points. In addition, we apply the same approach to a single nonlinear microcavity coupled with an atom and the critical atom-cavity coupling strength of the optical-hysteresis regime is also obtained. Finally, in order to illustrate that the critical point could be determined by the classical optical-bistability transformation, we analyze the Liouvillian gap and find it opens at the critical point of the optical-hysteresis regime. This work clarifies the relation between optical hysteresis and classical optical bistability, which provides theoretical references for the modulation of optical hysteresis in experiment.

In Phys. Rev. A 99, 032106 (2019), the authors claim that the almost-quantum set of correlations cannot reproduce two points on the boundary of the quantum set of correlations. This claim is incorrect. The underlying issue is that the associated semidefinite programming problem is not strictly feasible, which makes the numerical solvers give unreliable answers. We give analytical proofs that both points are indeed reproduced by the almost-quantum set.

We investigate the optimal charging processes for several models of quantum batteries, finding how to maximize the energy stored in a given battery with a finite-time modulation of a set of external fields. We approach the problem using advanced tools of optimal control theory, highlighting the universality of some features of the optimal solutions, for instance the emergence of the well-known bang-bang behavior of time-dependent external fields. The technique presented here is general, and we apply it to specific cases in which the energy is either pumped into the battery by external forces (direct charging) or transferred into it from an external charger (mediated charging). In this paper we focus on particular systems that consist of coupled qubits and harmonic oscillators, for which the optimal charging problem can be explicitly solved using a combined analytical-numerical approach based on our optimal control techniques. However, our approach can be applied to more complex setups, thus fostering the study of many-body effects in the charging process.

We explore the synchronization phenomenon in the quantum few-body system of spins with the nonlocal dissipation. Without the external driving, we find that the system can exhibit stable oscillatory behaviors in the long-time dynamics accompanied by the appearance of the purely imaginary eigenvalues of the Liouvillian. Moreover, the oscillations of the next-nearest-neighboring spins are completely synchronized, which is revealed by the quantum trajectory analysis within the stochastic Schrödinger equation. The possibility of the appearance of the long-time oscillations in an infinite-size lattice by means of cluster mean-field approximation is also discussed.

In this work we present a complete hybrid classical-quantum algorithm involving a quantum sampler based on neutral-atom platforms. This approach is inspired by classical column-generation frameworks developed in the field of operations research and shows how quantum procedures can assist classical solvers in addressing hard combinatorial problems. We benchmark our method on the minimum vertex coloring problem and show that the proposed hybrid quantum-classical column-generation algorithm can yield good solutions in relatively few iterations. We compare our results with state-of-the-art classical and quantum approaches.

The description of experimental data on energy and angular distributions of electrons produced in intermediate-energy proton collisions with ${\mathrm{H}}_2$ has remained an insurmountable problem for over five decades. A coupled-channel method is developed that provides an accurate solution to the problem. The doubly differential cross section as a function of the energy and angle of the ejected electron is calculated. Excellent agreement between the present results and the experimental data is found. This breakthrough in theoretical modeling of differential ionization in $p+{\mathrm{H}}_2$ collisions paves the way to accurate description of the recent kinematically complete experiments.