Additional superpromotion S series successively connecting an infinite number of ‖N,l,m〉-‖N+1,l,m〉 adiabatic states of a one-electron–two-Coulomb-center system (,e,) have been discovered in the complex plane of internuclear distance. The structure of the 5gσ series for the = system has been investigated in more detail. The additional superpromotion S series provide additional ionization channels in the (,e,) collision system, with a significant contribution to the total cross section for energies above -5 keV/u.