Electron-impact study of the NH radical using the -matrix method
Jasmeet Singh Rajvanshi and K. L. Baluja
Phys. Rev. A 82, 062710 (2010) - Published 16 December, 2010
We have employed the -matrix method to compute elastic (integrated and differential), momentum-transfer, excitation, and ionization cross sections for electron impact on the NH radical. The target states are represented by including correlations via a configuration interaction technique. The results of the static exchange, correlated one-state configuration interaction, and 19-state close-coupling approximation are presented. We have detected a stable anionic bound state of NH having the configuration . The data of the momentum-transfer cross section, generated from the differential cross section, is used to compute effective collision frequencies over a wide electron temperature range (– ). The ionization cross sections are calculated in the binary-encounter Bethe model in which Hartree-Fock molecular orbitals at self-consistent levels are used to calculate kinetic and binding energies of the occupied molecular orbitals. We have included up to the partial wave () in the scattering calculations. For this dipolar molecule we have used a Born-closure top-up procedure to account for the higher partial waves for the convergence of the cross section.