X-ray spectra of -shell hollow krypton atoms produced in single collisions with 52–197-MeV/u ions are measured in a heavy-ion storage ring equipped with an internal gas-jet target. Energy shifts of the , , and transitions are obtained. Thus the average number of the spectator vacancies presented during the x-ray emission is deduced. From the relative intensities of the and transitions, the ratio of -shell hollow krypton to singly -shell ionized atoms is determined to be . In the considered collisions, the vacancies are mainly created by the direct ionization which cannot be calculated within the perturbation descriptions. The experimental results are compared with a relativistic coupled-channel calculation performed within the independent particle approximation.