• Accepted Paper

Generalized Fourier’s law in mesoscopic systems

Luciano C. Lapas

APS Open Sci. - Accepted 4 November, 2026

DOI: https://doi.org/10.1103/ggz5-nggb

Abstract

Fourier’s law fails when the mean free path of the energy carriers becomes comparable to the length and time scales over which the temperature field varies. We derive a thermodynamically consistent generalization in which the conductivity becomes a nonlocal memory operator 𝛋eff(𝐤,ω), by combining mesoscopic nonequilibrium thermodynamics with the Mori–Kubo–Zwanzig projection-operator formalism. The Onsager kernel is a tensor sum over vibrational normal modes weighted by their Bose heat capacities and relaxation functions; it satisfies the second law for any closure consistent with the fluctuation–dissipation theorem and reduces, in the relaxation-time closure, to the nonlocal conductivity of the phonon Boltzmann equation. Two consequences follow. First, direction-dependent sampling of this tensor in a pump–probe experiment makes a nominally isotropic crystal exhibit apparent conductivities Λz≠Λr. Second, the modulation frequency does not introduce temporal memory but sets the probed wavevector through the thermal penetration depth, so that the frequency-dependent suppression of the apparent conductivity measured by time-domain thermoreflectance on Ge and SiGe alloys is a spatial-nonlocality effect, with effective lengths of 0.25–0.4μm. With published mean-free-path spectra and no parameter adjusted to the thermoreflectance data, the kernel reproduces the spot-size dependence of Si, the frequency dependence of the apparent conductivity of Ge and Si0.2Ge0.8 and the rise of the apparent interface conductance of Al/Si0.99Ge0.01, and contains the two-channel ballistic/diffusive model as a two-sector projection.

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