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Flexophotovoltaic Effect and Above-Band-Gap Photovoltage Induced by Strain Gradients in Halide Perovskites
Phys. Rev. Lett. 132, 086902 – Published 20 February, 2024
DOI: https://doi.org/10.1103/PhysRevLett.132.086902
Abstract
We have measured the flexophotovoltaic effect of single crystals of halide perovskites and , as well as the benchmark oxide perovskite . For halide perovskites, the flexophotovoltaic effect is found to be orders of magnitude larger than for , and indeed large enough to induce photovoltages bigger than the band gap. Moreover, we find that in the flexophotovoltaic effect is additional to a native bulk photovoltaic response that is switchable and ferroelectric-like. The results suggest that strain gradient engineering can be a powerful tool to modify the photovoltaic output even in already well-established photovoltaic materials.
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