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    Order-Disorder Ferroelectric Transition of Strained SrTiO3

    Salva Salmani-Rezaie, Kaveh Ahadi, William M. Strickland, and Susanne Stemmer*

    • Materials Department, University of California, Santa Barbara, California 93106-5050, USA

    • *Corresponding author. stemmer@mrl.ucsb.edu

    Phys. Rev. Lett. 125, 087601 – Published 20 August, 2020

    DOI: https://doi.org/10.1103/PhysRevLett.125.087601

    Abstract

    SrTiO3 is an incipient ferroelectric that is believed to exhibit a prototype displacive, soft mode ferroelectric transition when subjected to mechanical stress or alloying. We use high-angle annular dark-field imaging in scanning transmission electron microscopy to reveal local polar regions in the room-temperature, paraelectric phase of strained SrTiO3 films, which undergo a ferroelectric transition at low temperatures. These films contain nanometer-sized domains in which the Ti columns are displaced. In contrast, these nanodomains are absent in unstrained films, which do not become ferroelectric. The results show that the ferroelectric transition of strained SrTiO3 is an order-disorder transition. We discuss the impact of the results on the nature of the ferroelectric transition of SrTiO3.

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