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    Multiferroicity in the Two-Dimensional Limit in Hexagonal LuFeO3 Films

    Huilin Lai1,2, Junyu Tan1,2, Jinfeng Zhai1,2, Yang Shi1,2, Lili Feng1,2, Huanyu Zhang1,2, Chuanrui Huo3, Chuhang Liu4, Lijun Wu4 et al.

    Lifeng Yin1,2,5,6,7, Hangwen Guo1,2,5, Jun Chen3, Xiaoshan Xu8, Jun Zhao1,2,5,6, Yimei Zhu4, Shiqing Deng3,*, Wenbin Wang1,2,5,†, and Jian Shen1,2,5,6,7,‡

    • *Contact author: sqdeng@ustb.edu.cn
    • †Contact author: wangwb@fudan.edu.cn
    • ‡Contact author: shenj5494@fudan.edu.cn

    Phys. Rev. Lett. 137, 026801 – Published 7 July, 2026

    DOI: https://doi.org/10.1103/zxsb-7cj3

    Abstract

    Multiferroic oxides, which host coexisting ferroelectric and magnetic orders, are central to understanding correlated quantum phenomena. Yet, as thickness approaches the two-dimensional (2D) limit, both ferroelectricity and magnetism are generally expected to be strongly suppressed by depolarization fields and finite-size effects, respectively. Here, we show that hexagonal LuFeO3 (h−LuFeO3) retains multiferroic behavior down to a thickness of only one and a half unit cells. The polar structural distortion remains robust at room temperature and is comparable to that of the bulk, while robust magnetic order persists at low temperatures. We further find that the magnetic response can be reproducibly modulated through ferroelectric domain-state control. Structural analysis indicates that the K3 distortion remains stable down to the two-dimensional limit, providing the basis for the survival of improper ferroelectricity in this regime. These results establish h−LuFeO3 as an oxide platform in which ferroelectricity and magnetic order coexist at the atomic-scale limit, and provide insight into how coupled ferroic behavior can persist in ultrathin complex oxides.

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