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Extending the Observation Time of Charged Helium Droplets to the Minute Timescale
Phys. Rev. Lett. 136, 013201 – Published 5 January, 2026
DOI: https://doi.org/10.1103/yr98-h791
Abstract
We report on the successful trapping of micrometer-sized, multiply-charged helium droplets over periods of several seconds up to a minute—the first observation of trapped charged helium droplets. Within a meter-long multireflection mass spectrometer, the droplets complete thousands of revolutions, opening up new possibilities for precision measurements of these unique systems. Their confinement is limited by collisions with residual gas, which gradually reduce their kinetic energy through evaporation of helium atoms from the droplet and prevent extraction from the trap below a critical value. The rate of energy loss is strongly influenced not only by the residual gas density, but also by the type of species picked up by the droplets. In particular, infrared absorption by water cluster ions inside the droplets enhances energy transfer to the helium matrix, leading to accelerated evaporation of helium atoms.
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References (42)
- J. I. Cirac and P. Zoller, Quantum computations with cold trapped ions, Phys. Rev. Lett. 74, 4091 (1995).
- S. Alighanbari, G. S. Giri, F. L. Constantin, V. I. Korobov, and S. Schiller, Precise test of quantum electrodynamics and determination of fundamental constants with HD + ions, Nature (London) 581, 152 (2020).
- M. Nötzold, R. Wild, C. Lochmann, T. Rahim, S. P. Melath, K. Dulitz, B. Mant, J. Franz, F. A. Gianturco, and R. Wester, Vibrational quenching of optically pumped carbon dimer anions, Phys. Rev. Lett. 131, 183002 (2023).
- A. Kilaj, H. Gao, D. Rösch, U. Rivero, J. Küpper, and S. Willitsch, Observation of different reactivities of para and ortho-water towards trapped diazenylium ions, Nat. Commun. 9, 2096 (2018).
- M. Perdriat, C. C. Rusconi, T. Delord, P. Huillery, C. Pellet-Mary, A. Durand, B. A. Stickler, and G. Hétet, Rotational locking of charged microparticles in quadrupole ion traps, Phys. Rev. Lett. 133, 253602 (2024).
- L. S. Brown and G. Gabrielse, Geonium theory: Physics of a single electron or ion in a Penning trap, Rev. Mod. Phys. 58, 233 (1986).
- G. Gabrielse, A. Khabbaz, D. S. Hall, C. Heimann, H. Kalinowsky, and W. Jhe, Precision mass spectroscopy of the antiproton and proton using simultaneously trapped particles, Phys. Rev. Lett. 82, 3198 (1999).
- A. G. Marshall, C. L. Hendrickson, and G. S. Jackson, Fourier transform ion cyclotron resonance mass spectrometry: A primer, Mass Spectrom. Rev. 17, 1 (1998).
- R. Wester, Radiofrequency multipole traps: Tools for spectroscopy and dynamics of cold molecular ions, J. Phys. B 42, 154001 (2009).
- D. Zajfman, O. Heber, L. Vejby-Christensen, I. Ben-Itzhak, M. Rappaport, R. Fishman, and M. Dahan, Electrostatic bottle for long-time storage of fast ion beams, Phys. Rev. A 55, R1577 (1997).
- R. Wolf, F. Wienholtz, D. Atanasov, D. Beck, K. Blaum, Ch. Borgmann, F. Herfurth, M. Kowalska, S. Kreim, Yu. A. Litvinov, D. Lunney, V. Manea, D. Neidherr, M. Rosenbusch, L. Schweikhard, J. Stanja, and K. Zuber, ISOLTRAP’s multi-reflection time-of-flight mass separator/spectrometer, Int. J. Mass Spectrom. 349–350, 123 (2013).
- R. von Hahn et al., The cryogenic storage ring CSR, Rev. Sci. Instrum. 87, 063115 (2016).
- C. J. Herrlander, L. Bagge, A. Barany, S. Borg, H. Danared, P. Heikkinen, S. Hultberg, L. Liljeby, and Th. Lindblad, Cryring—a small storage and acceleration ring for heavy ions, IEEE Trans. Nucl. Sci. 32, 2718 (1985).
- H. T. Schmidt et al., First storage of ion beams in the double electrostatic ion-ring experiment: DESIREE, Rev. Sci. Instrum. 84, 055115 (2013).
- J. Labaziewicz, Y. Ge, P. Antohi, D. Leibrandt, K. R. Brown, and I. L. Chuang, Suppression of heating rates in cryogenic surface-electrode ion traps, Phys. Rev. Lett. 100, 013001 (2008).
- N. Heine and K. R. Asmis, Cryogenic ion trap vibrational spectroscopy of hydrogen-bonded clusters relevant to atmospheric chemistry, Int. Rev. Phys. Chem. 34, 1 (2015).
- E. K. Campbell, M. Holz, D. Gerlich, and J. P. Maier, Laboratory confirmation of as the carrier of two diffuse interstellar bands, Nature (London) 523, 322 (2015).
- J. Oomens, B. G. Sartakov, G. Meijer, and G. von Helden, Gas-phase infrared multiple photon dissociation spectroscopy of mass-selected molecular ions, Int. J. Mass Spectrom. 254, 1 (2006).
- S. Willitsch, M. T. Bell, A. D. Gingell, S. R. Procter, and T. P. Softley, Cold reactive collisions between laser-cooled ions and velocity-selected neutral molecules, Phys. Rev. Lett. 100, 043203 (2008).
- A. B. Wolk, C. M. Leavitt, E. Garand, and M. A. Johnson, Cryogenic ion chemistry and spectroscopy, Acc. Chem. Res. 47, 202 (2014).
- J. Roithová, A. Gray, E. Andris, J. Jašík, and D. Gerlich, Helium tagging infrared photodissociation spectroscopy of reactive ions, Acc. Chem. Res. 49, 223 (2016).
- J. Jašík, J. Žabka, J. Roithová, and D. Gerlich, Infrared spectroscopy of trapped molecular dications below 4 K, Int. J. Mass Spectrom. Detlef Schröder Memorial Issue, 354–355, 204 (2013).
- S. Debnath, A. Schäfer, S. Ito, D. Strelnikov, R. Schneider, K. A. Haupa, and M. M. Kappes, Vibrationally resolved absorption, fluorescence, and preresonance Raman spectroscopy of isolated pyronin Y cation at 5 K, J. Phys. Chem. Lett. 14, 10553 (2023).
- M. Kuhn, M. Renzler, J. Postler, S. Ralser, S. Spieler, M. Simpson, H. Linnartz, A. G. G. M. Tielens, J. Cami, A. Mauracher, Y. Wang, M. Alcamí, F. Martín, M. K. Beyer, R. Wester, A. Lindinger, and P. Scheier, Atomically resolved phase transition of fullerene cations solvated in helium droplets, Nat. Commun. 7, 13550 (2016).
- L. Tiefenthaler, J. Ameixa, P. Martini, S. Albertini, L. Ballauf, M. Zankl, M. Goulart, F. Laimer, K. von Haeften, F. Zappa, and P. Scheier, An intense source for cold cluster ions of a specific composition, Rev. Sci. Instrum. 91, 033315 (2020).
- P. Martini, S. Albertini, F. Laimer, M. Meyer, M. Gatchell, O. Echt, F. Zappa, and P. Scheier, Splashing of large helium nanodroplets upon surface collisions, Phys. Rev. Lett. 127, 263401 (2021).
- A. Iguchi, A. Hirota, S. Menk, T. Yamaguchi, H. Tanuma, J. R. Harries, S. Kuma, and T. Azuma, Size distribution of helium droplets in the condensation regime of a pulsed beam, Low Temp. Phys. 50, 802 (2024).
- F. Laimer, F. Zappa, and P. Scheier, Size and velocity distribution of negatively charged helium nanodroplets, J. Phys. Chem. A 125, 7662 (2021).
- C. D. Brown, Y. Wang, M. Namazi, G. I. Harris, M. T. Uysal, and J. G. E. Harris, Superfluid helium drops levitated in high vacuum, Phys. Rev. Lett. 130, 216001 (2023).
- F. Laimer, L. Kranabetter, L. Tiefenthaler, S. Albertini, F. Zappa, A. M. Ellis, M. Gatchell, and P. Scheier, Highly charged droplets of superfluid helium, Phys. Rev. Lett. 123, 165301 (2019).
- S. Bergmeister, L. Ganner, J. Locher, F. Zappa, P. Scheier, and E. Gruber, Spectroscopy of helium-tagged molecular ions-development of a novel experimental setup, Rev. Sci. Instrum. 94, 055105 (2023).
- R. C. Dunbar, BIRD (blackbody infrared radiative dissociation): Evolution, principles, and applications, Mass Spectrom. Rev. 23, 127 (2004).
- M. Schlaich, J. Fischer, P. Fischer, C. Klink, A. Obertelli, A. Schmidt, L. Schweikhard, and F. Wienholtz, A multi-reflection time-of-flight mass spectrometer for the offline ion source of the PUMA experiment, Int. J. Mass Spectrom. 495, 117166 (2024).
- G. Niedner-Schatteburg and V. E. Bondybey, FT-ICR studies of solvation effects in ionic water cluster reactions, Chem. Rev. 100, 4059 (2000).
- L. F. Gomez, E. Loginov, R. Sliter, and A. F. Vilesov, Sizes of large He droplets, J. Chem. Phys. 135, 154201 (2011).
- F. Laimer, F. Zappa, E. Gruber, and P. Scheier, Electron ionization of size-selected positively and negatively charged helium droplets, Atoms 9, 74 (2021).
- A. Malloum, J. J. Fifen, Z. Dhaouadi, S. G. N. Engo, and J. Conradie, Structures, relative stability and binding energies of neutral water clusters, , New J. Chem. 43, 13020 (2019).
- M. F. Jarrold, Applications of charge detection mass spectrometry in molecular biology and biotechnology, Chem. Rev. 122, 7415 (2022).
- E. Hanozin, C. C. Harper, M. S. McPartlan, and E. R. Williams, Dynamics of rayleigh fission processes in charged aqueous nanodrops, ACS Cent. Sci. 9, 1611 (2023).
- P. Fischer and L. Schweikhard, Decay-rate power-law exponent as a link between dissociation energy and temperature, Phys. Rev. Res. 2, 043177 (2020).
- C. Breitenfeldt, K. Blaum, M. W. Froese, S. George, G. Guzmán-Ramírez, M. Lange, S. Menk, L. Schweikhard, and A. Wolf, Decay processes and radiative cooling of small anionic copper clusters, Phys. Rev. A 94, 033407 (2016).
- M. Veternik, T. Waldhütter, L. Schweikhard, P. Scheier, and E. Gruber, Extending the observation time of charged helium droplets to the minute timescale, 10.5281/zenodo.17085555 (2025).