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    Quantum Geometry in Phonon-Mediated Optical Responses

    Jiaming Hu1,2,3,4, Wenbin Li2,3,1,*, Zhichao Guo4, Hua Wang4,†, and Kai Chang4

    • 1School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
    • 2Department of Materials Science and Engineering, Westlake University, Hangzhou 310030, China
    • 3Zhejiang Key Laboratory of 3D Micro/Nano Fabrication and Characterization, Westlake University, Hangzhou 310030, China
    • 4Center for Quantum Matter, School of Physics, Zhejiang University, Hangzhou 310058, China

    • *Contact author: liwenbin@westlake.edu.cn
    • †Contact author: daodaohw@zju.edu.cn

    Phys. Rev. Lett. 135, 256404 – Published 18 December, 2025

    DOI: https://doi.org/10.1103/y66p-kjj7

    Abstract

    Quantum geometry is crucial for understanding intricate condensed matter systems, governing transport phenomena and optical responses. However, traditional studies of quantum geometry predominantly consider a static crystal lattice, focusing exclusively on the pure-electronic quantum geometry of the Hilbert space parametrized by electronic wave vectors, thereby overlooking the dynamic effects arising from phonons and their coupling with electrons. In this Letter, we reveal the intrinsic quantum geometry of the electron-phonon coupling (EPC), which resides in the hybrid Hilbert space parametrized by both the electronic wave vectors and phonon displacements. The EPC quantum metric, EPC Berry curvature, and EPC shift vector, as central elements, quantify the EPC-induced velocity, polarization, and anomalous charge-center shift, respectively. We further connect this geometry to phonon-mediated optical responses, particularly in-gap resonances, enabling experimental detection and characterization of EPC quantum geometry.

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    See Also

    Quantum Geometric Origin of Strain-Induced Ferroelectric Phase Transitions

    Jiaming Hu, Ziye Zhu, Yubo Yuan, Hua Wang, and Kai Chang
    Phys. Rev. Lett. 135, 256405 (2025)

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