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    Unlocking Static Polarization and Strain Density Waves in Perovskites by Softening a Hidden Antiferrodistortive Tilt Gradient Mode

    Yajun Zhang1,2,3, Devesh R. Kripalani3, Xu He4, Konstantin Shapovalov4, Jiyuan Yang5, Hongjian Zhao6, Shi Liu5, Huadong Yong1,2,*, Xingyi Zhang1,2,† et al.

    Jie Wang7, Kun Zhou3,‡, and Philippe Ghosez4

    • 1Key Laboratory of Mechanics on Disaster and Environment in Western China Attached to The Ministry of Education of China, Lanzhou University, Lanzhou 730000, Gansu, China
    • 2Department of Mechanics and Engineering Science, College of Civil Engineering and Mechanics, Lanzhou University, Lanzhou 730000, Gansu, China
    • 3School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798, Singapore
    • 4Theoretical Materials Physics, Q-MAT, Université de Liège, B-4000 Liège, Belgium
    • 5Department of Physics, School of Science, Westlake University, Hangzhou 310024, China
    • 6Key Laboratory of Material Simulation Methods and Software of Ministry of Education, College of Physics, Jilin University, Changchun 130012, China
    • 7Department of Engineering Mechanics, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China

    • *Contact author: yonghd@lzu.edu.cn
    • †Contact author: zhangxingyi@lzu.edu.cn
    • ‡Contact author: kzhou@ntu.edu.sg

    Phys. Rev. Lett. 137, 086101 – Published 18 August, 2026

    DOI: https://doi.org/10.1103/xlvk-k52x

    Abstract

    Spin density waves (SDWs) represent a fundamental paradigm of spatially modulated order in condensed matter systems, yet their electrical and mechanical analogs—polarization and strain density waves (PDWs and StDWs)—have remained elusive as equilibrium phases. Here, we introduce a general, symmetry-driven strategy to unlock static PDWs and StDWs in perovskites SrTiO3 and SrMnO3. Using first-principles calculations, we uncover a previously overlooked soft antiferrodistortive tilt gradient mode at small-q wave vector in the phonon dispersion of their presumed Ima2 ground state under moderate tensile strain. Group-theory analysis reveals that a hard polar-acoustic phonon, which intrinsically carries PDWs and StDWs, is improperly destabilized by a trilinear coupling with this modulated tilt mode and an inherently uniform tilt mode. This interaction drives a structural transition from the Ima2 phase to a novel lower-energy Pmn21 phase that hosts long-range-ordered PDWs and StDWs. Strikingly, the engineered StDWs in SrMnO3 activate an electrically tunable SDW via the flexomagnetic effect. These discoveries fundamentally revise the strain-phase diagrams of prototypical perovskites and establish a unified phonon engineering framework that links modulated phonon instabilities to targeted density-wave order, offering new pathways for designing advanced electromechanical and magnetoelectric functionalities.

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