Importance of Nonadiabatic Effects in Kohn Anomalies in 1D Metals
Phys. Rev. Lett. 135, 256402 – Published 17 December, 2025
DOI: https://doi.org/10.1103/x69r-8fw1
Abstract
Kohn anomalies are kinks or dips in phonon dispersions which are pronounced in low-dimensional materials. We investigate the effects of nonadiabatic phonon self-energy on Kohn anomalies in one-dimensional metals by developing a model that analyzes how the adiabatic phonon frequency, electron effective mass, and electron-phonon coupling strength influence phonon mode renormalization. We introduce an electron-phonon coupling strength threshold for low-temperature system instability, providing experimentalists with a tool to predict them. Finally, we validate the predictions of our model against first-principles calculations on a 4 Å-diameter carbon nanotube.