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Anomalous Terahertz Nonlinearity in Disordered s-Wave Superconductor Close to the Superconductor-Insulator Transition

Hao Wang1, Jiayu Yuan1, Hongkai Shi2, Haojie Li2, Xiaoqing Jia2, Xiaohui Song3, Liyu Shi1, Tianyi Wu1, Li Yue4 et al.

Yangmu Li3,5, Kui Jin3,5,6, Dong Wu4, Jianlin Luo3, Xinbo Wang3,*, Tao Dong1,†,‡, and Nan-Lin Wang1,4,†,§

  • *Contact author: xinbowang@iphy.ac.cn
  • †Present address: Tsung-Dao Lee Institute, Shanghai Jiao Tong University, Shanghai 201210, China.
  • ‡Contact author: taodong@sjtu.edu.cn
  • §Contact author: nlwang@sjtu.edu.cn

Phys. Rev. Lett. 136, 146004 – Published 10 April, 2026

DOI: https://doi.org/10.1103/t5wx-z86b

Abstract

Detection of the Higgs mode in superconductors using nonlinear terahertz spectroscopy is a key area of interest in condensed matter physics. We investigate the influence of disorder on the nonlinear terahertz response and the Higgs mode in NbN thin films with varying Ioffe-Regel parameters (kFl). In strongly disordered films near the superconductor-insulator transition, we observe an anomalous third-harmonic generation (THG) signal above Tc, which is absent in both cleaner superconducting and nonsuperconducting counterparts. The persistence of this normal-state THG signal in a high magnetic field excludes superconducting fluctuations as its origin. Below Tc, the THG intensity increases sharply, indicating a dominant contribution from the driven Higgs mode. The THG spectrum of the strongly disordered sample exhibits a broadened, multipeak structure, which we attribute to quantum path interference between distinct channels involving unpaired electrons and Cooper pairs within emergent superconducting islands. Our findings not only demonstrate how disorder tunes the nonlinear terahertz response, but also uncover a strong coupling between electrons responsible for normal-state THG and the superconducting Higgs mode below Tc in strongly disordered samples.

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