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    Creation of Ultracold Heteronuclear p-Wave Feshbach Molecules

    Fan Jia1,*,†, Zhichao Guo1,‡, Zerong Huang1,2, and Dajun Wang1,2,§

    • *Contact author: fan.jia@mpq.mpg.de
    • †Present address: Max Planck Institute of Quantum Optics, Garching, Germany.
    • ‡Present address: Department of Applied Physics and Science Education, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands.
    • §Contact author: djwang@cuhk.edu.hk

    Phys. Rev. Lett. 137, 093001 – Published 26 August, 2026

    DOI: https://doi.org/10.1103/smgh-m2yq

    Abstract

    We report the first creation of a bulk sample of ultracold heteronuclear p-wave Feshbach molecules in an optically trapped Bose-Bose mixture of Na23 and Rb87 atoms. Using loss spectroscopy and binding energy measurements, we systematically characterize the interspecies p-wave Feshbach resonances near 284 G. Leveraging this understanding, we use magnetoassociation to form p-wave NaRb Feshbach molecules, producing both pure samples and mixtures of molecules in different p-wave orbitals. We further measure the molecular lifetime and identify atom-molecule and molecule-molecule collisions as the dominant loss mechanisms. This Letter establishes a previously unavailable ultracold molecule platform that combines orbital anisotropy with heteronuclear constituents, represents a significant step toward realizing tunable p-wave interactions in Bose-Bose mixtures, and provides a foundation for exploring nonzero angular momentum molecules.

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