Creation of Ultracold Heteronuclear -Wave Feshbach Molecules
Phys. Rev. Lett. 137, 093001 – Published 26 August, 2026
DOI: https://doi.org/10.1103/smgh-m2yq
Abstract
We report the first creation of a bulk sample of ultracold heteronuclear -wave Feshbach molecules in an optically trapped Bose-Bose mixture of and atoms. Using loss spectroscopy and binding energy measurements, we systematically characterize the interspecies -wave Feshbach resonances near 284 G. Leveraging this understanding, we use magnetoassociation to form -wave NaRb Feshbach molecules, producing both pure samples and mixtures of molecules in different -wave orbitals. We further measure the molecular lifetime and identify atom-molecule and molecule-molecule collisions as the dominant loss mechanisms. This Letter establishes a previously unavailable ultracold molecule platform that combines orbital anisotropy with heteronuclear constituents, represents a significant step toward realizing tunable -wave interactions in Bose-Bose mixtures, and provides a foundation for exploring nonzero angular momentum molecules.