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    Universal Phonon-Mediated Superconductivity in Compressed Metal Monochalcogenides beyond Anderson Localization

    Ertuğrul Karaca1,2, Fang Hong3,4,*, and Daniel Errandonea5,†

    • *Contact author: hongfang@iphy.ac.cn
    • †Contact author: daniel.errandonea@uv.es

    Phys. Rev. Lett. 136, 246001 – Published 16 June, 2026

    DOI: https://doi.org/10.1103/rbzb-km7n

    Abstract

    High-pressure superconductivity in metal monochalcogenides has been ascribed to disorder-driven Anderson localization [Phys. Rev. Lett. 134, 196001 (2025)]. Using density-functional perturbation theory and Migdal-Eliashberg calculations, we show that superconductivity in BiSe, PbSe, PbS, and HgS is instead governed by a universal intrinsic mechanism. Under pressure, the superconducting transition temperature is fully regulated by conventional electron-phonon coupling and decreases monotonically with pressure due to phonon hardening and a reduced density of states at the Fermi level. The increase of Tc previously reported upon decompression arises from the recovery of stronger intrinsic coupling in metastable low-pressure phases, without invoking disorder or localization effects previously used to explain this phenomenon. Our results establish a unified phonon-mediated description of superconductivity in metal monochalcogenides and solve conflicting interpretations.

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