Material Realization of Spinless, Covalent-Type Dirac Semimetals in Three Dimensions
Phys. Rev. Lett. 137, 096603 – Published 26 August, 2026
DOI: https://doi.org/10.1103/pshy-l48q
Abstract
Realization of a three-dimensional (3D) analog of graphene has been a central challenge in topological materials science. Graphene is stabilized by covalent bonding, unlike conventional spin-orbit-type 3D Dirac semimetals (DSMs). In this study, we demonstrate the material realization of covalent-type 3D DSMs stabilized by covalent bonding. We confirm the clean Dirac semimetal state in by combined thermodynamic and transport experiments. We also realize high carrier mobility exceeding even in polycrystalline samples of . Our research provides a material platform for exploration of Dirac electrons in three dimensions with wide chemical tunability.