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Ising Supercriticality and Universal Magnetocalorics in Spiral Antiferromagnet Nd3BWO9

Xinyang Liu1,2,3,*, Enze Lv4,5,*, Xueling Cui1,*, Han Ge6,*, Fangyuan Song7, Zhaoming Tian7, Gang Su4, Kan Zhao1,†, Junsen Xiang2,‡ et al.

Peijie Sun2,§ and Wei Li4,3,∥

  • *These authors contributed equally to this work.
  • †Contact author: kan_zhao@buaa.edu.cn
  • ‡Contact author: xiangjs@iphy.ac.cn
  • §Contact author: pjsun@iphy.ac.cn
  • ∥Contact author: w.li@itp.ac.cn

Phys. Rev. Lett. 136, 246502 – Published 17 June, 2026

DOI: https://doi.org/10.1103/nqcw-pz8v

Abstract

The celebrated analogy between the pressure-temperature phase diagram of a liquid-gas system and the field-temperature phase diagram of a ferromagnet has long been a cornerstone for understanding universality of phase transitions and critical phenomena. Here we extend this analogy to a highly frustrated antiferromagnet, the spiral Ising compound Nd3BWO9 with kagome layers. In its phase diagram, we identify a metamagnetic transition line with a critical endpoint (CEP) located at μ0Hc≃1.04  T and Tc≃0.3  K. Above the CEP, an Ising supercritical regime emerges with crossover lines that follow a universal scaling law, as evidenced by the specific heat, magnetic susceptibility, and magnetocaloric measurements. Remarkably, we observe critically enhanced magnetic cooling near the emergent CEP, characterized by a divergent magnetic Grüneisen ratio ΓH∝1/tβ+γ−1, with β+γ≃1.563 the sum of critical exponents of the 3D Ising universality class and t≡(T−Tc)/Tc the reduced temperature. Adiabatic demagnetization from 2 K and 4 T reaches a minimum temperature of 195 mK, via a self-cascading process that combines supercritical and topological cooling. Our findings open a new avenue for studying supercritical phenomena and magnetic refrigeration with the frustrated rare-earth compounds RE3BWO9 and, more broadly, in Ising-anisotropic antiferromagnets such as spin ices.

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