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    Common Sublattice-Pure Van Hove Singularities in the Kagome Superconductors AV3Sb5 (A=K, Rb, Cs)

    Yujie Lan1,2,3,*, Yuhao Lei1,2,3,*, Congcong Le4,5,*, Brenden R. Ortiz6, Nicholas C. Plumb7, Milan Radovic7, Xianxin Wu8,†, Ming Shi9,10,11, Stephen D. Wilson6 et al.

    Yong Hu1,2,3,‡

    • *These authors contributed equally to this work.
    • †Contact author: xxwu@itp.ac.cn
    • ‡Contact author: yong.hu@cqu.edu.cn

    Phys. Rev. Lett. 136, 016401 – Published 2 January, 2026

    DOI: https://doi.org/10.1103/njg9-jpkh

    Abstract

    Kagome materials offer a versatile platform for exploring correlated and topological quantum states, where Van Hove singularities (VHSs) play a pivotal role in driving electronic instabilities, exhibiting distinct behaviors depending on electron filling and interaction settings. In the recently discovered kagome superconductors AV3Sb5 (A=K, Rb, Cs), unconventional charge density wave order, superconductivity, and electronic chirality emerge, yet the nature of VHSs near the Fermi level (EF) and their connection to these exotic orders remain elusive. Here, using high-resolution polarization-dependent angle-resolved photoemission spectroscopy, we uncover a universal electronic structure across AV3Sb5 that is distinct from density-functional theory predictions that show noticeable discrepancies. We identify multiple common sublattice-pure VHSs near EF, arising from strong V−d/Sb−p hybridization, which significantly promote bond-order fluctuations and likely drive the observed charge density wave order. These findings provide direct spectroscopic evidence for hybridization-driven VHS formation in kagome metals and establish a unified framework for understanding the intertwined electronic instabilities in AV3Sb5.

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