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    Soft Phonon Charge-Density-Wave Formation in the Kagome Metal KV3Sb5

    Yifan Wang1,*, Chenchao Xu2,*, Zhimian Wu3, Huachen Rao3, Zhaoyang Shan1, Yi Liu4,5, Guanghan Cao4,6,7, Michael Smidman1, Ming Shi1,8 et al.

    Huiqiu Yuan1,6,7,8, Tao Wu3, Xianhui Chen3, Chao Cao1,†, and Yu Song1,‡

    • *These authors contributed equally to this work.
    • †Contact author: ccao@zju.edu.cn
    • ‡Contact author: yusong_phys@zju.edu.cn

    Phys. Rev. Lett. 136, 136401 – Published 31 March, 2026

    DOI: https://doi.org/10.1103/lhfz-7tk1

    Abstract

    A range of unusual emergent behaviors have been reported in the charge-density-wave (CDW) state of the AV3Sb5 (A=K, Rb, Cs) kagome metals, including a CDW formation process without soft phonons, which points to an unconventional CDW mechanism. Here, we use inelastic x-ray scattering to show that the CDW in KV3Sb5 forms via phonons that soften to zero energy at the CDW ordering vector (L point) around TCDW=78  K. The intensity of soft phonons exhibits a remarkable in-plane anisotropy, extending over a much larger momentum range along L−A relative to L−H, which leads to diffuse scattering common among AV3Sb5. Using first-principles calculations, we find that the momentum-dependent electron-phonon coupling (EPC) peaks at L and exhibits the same in-plane anisotropy as the phonon softening. Conversely, the electronic susceptibility does not peak at L and shows the opposite in-plane anisotropy. Our findings favor momentum-dependent EPC as the driving mechanism of the CDW in KV3Sb5, with a CDW formation process similar to that of transition metal dichalcogenides.

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