Soft Phonon Charge-Density-Wave Formation in the Kagome Metal
Phys. Rev. Lett. 136, 136401 – Published 31 March, 2026
DOI: https://doi.org/10.1103/lhfz-7tk1
Abstract
A range of unusual emergent behaviors have been reported in the charge-density-wave (CDW) state of the (, Rb, Cs) kagome metals, including a CDW formation process without soft phonons, which points to an unconventional CDW mechanism. Here, we use inelastic x-ray scattering to show that the CDW in forms via phonons that soften to zero energy at the CDW ordering vector ( point) around . The intensity of soft phonons exhibits a remarkable in-plane anisotropy, extending over a much larger momentum range along relative to , which leads to diffuse scattering common among . Using first-principles calculations, we find that the momentum-dependent electron-phonon coupling (EPC) peaks at and exhibits the same in-plane anisotropy as the phonon softening. Conversely, the electronic susceptibility does not peak at and shows the opposite in-plane anisotropy. Our findings favor momentum-dependent EPC as the driving mechanism of the CDW in , with a CDW formation process similar to that of transition metal dichalcogenides.