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    Decoupling Structure and Elasticity in Colloidal Gels Under Isotropic Compression

    M. Milani1,*,†, E. Cavalletti1, V. Ruzzi1, A. Martinelli1, P. Dieudonné-George1, C. Ligoure1, T. Phou1, L. Cipelletti1,2,‡, and L. Ramos1,‡,§

    • *Contact author: matteo.milani@espci.fr
    • †Present address: PMMH ESPCI, Paris, France.
    • ‡These authors contributed equally to this work.
    • §Contact author: laurence.ramos@umontpellier.fr

    Phys. Rev. Lett. 136, 038201 – Published 21 January, 2026

    DOI: https://doi.org/10.1103/kjks-x7n9

    Abstract

    We exploit the controlled drying of millimeter-sized gel beads to investigate the isotropic compression of colloidal fractal gels. Using a custom dynamic light scattering setup, we demonstrate that stresses imposed by drying on the bead surface propagate homogeneously throughout the gel volume, inducing plastic rearrangements. We find that the Young modulus and yield stress of the gels increase monotonically with the instantaneous colloid volume fraction, φ, exhibiting a mechanical response that depends solely on φ, regardless of the drying history. In striking contrast, small-angle x-ray scattering reveals that the gel microstructure retains a strong memory of its initial state, depending on both φ and the entire compression pathway. Our findings challenge the prevailing paradigm of a one-to-one relationship between microstructure and elasticity in colloidal fractal gels, opening new avenues for independent control over the structural and mechanical properties of soft materials.

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