The spontaneous emergence of chirality in crystalline solids has profound implications for electronic, optical, and topological properties, making the control of chiral phases a central challenge in materials design. Here, we investigate the structural and electronic properties of a new family of layered compounds, ${\mathrm{NbOX}}_2$, and explore the connection between their achiral $Immm$ phase and chiral $C2$ phase. Through first-principles calculations, we identify an intermediate achiral $C2/m$ phase that bridges the high- and low-symmetry phases within a three-dimensional order parameter space. By analyzing the Born-Oppenheimer energy surfaces, we find that the shallow energy minima of the $C2/m$ phase suggest it may be stabilized either by external factors such as pressure, as demonstrated here, or by ionic quantum or thermal fluctuations and the resulting lattice anharmonicity. Additionally, we show how an external electric field, by breaking the necessary symmetries, biases the system toward a preferred chirality by lifting the energy degeneracy between the two enantiomers. This, combined with the small energy barrier between the enantiomers in the $C2$ phase, enables handedness control and allows us to propose a mechanism for selective handedness stabilization by leveraging electric fields and pressure or temperature-dependent anharmonic effects. Our findings establish a framework for understanding chirality emergence in layered materials and offer a pathway for designing systems with tunable enantiomeric populations.

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• Charge density waves
• Order parameters
• Surface states
• Topological materials
• Dielectrics
• Ferroelectrics
• Chiral symmetry
• Density functional theory
• Quantum chemistry methods