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From Triangular Correlated Paramagnet to Multi- Noncoplanar Spin State in Spinel
Phys. Rev. Lett. 136, 016703 – Published 7 January, 2026
DOI: https://doi.org/10.1103/jl6t-ymd1
Abstract
Combining macroscopic measurements, neutron scattering, and modeling, we identify in the spinel a correlated paramagnetic state resulting from the predominance of third-neighbor antiferromagnetic interactions. These interactions materialize four interlaced families of triangular planes with 120° spins emerging from the underlying pyrochlore lattice. At lower temperatures, a phase transition occurs to a noncoplanar spin structure that is characterized by six propagation vectors. This unusual multi- order is triggered by the presence of weaker interactions up to the sixth neighbors. The system is remarkably successful in coupling the different triangular planes while maintaining their two-dimensional 120° order. Our Letter highlights the hierarchy of interactions involved in , which is singular among spinel compounds since first-neighbor interactions are only a small fraction of the dominant third-neighbor ones.