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From Triangular Correlated Paramagnet to Multi-q Noncoplanar Spin State in Spinel GeFe2O4

L. Chaix1,*, J. Robert1, E. Chan1, E. Ressouche2, S. Petit3, C. V. Colin1, R. Ballou1, J. Ollivier4, L.-P. Regnault2 et al.

E. Lhotel1, V. Cathelin1, S. Lenne1,†, C. Cavenel1, F. Damay3, E. Suard4, P. Strobel1, C. Darie1, S. deBrion1, and V. Simonet1

  • *Contact author: laura.chaix@neel.cnrs.fr
  • †Present address: School of Physics, CRANN, Trinity College, Dublin 2, Ireland.

Phys. Rev. Lett. 136, 016703 – Published 7 January, 2026

DOI: https://doi.org/10.1103/jl6t-ymd1

Abstract

Combining macroscopic measurements, neutron scattering, and modeling, we identify in the GeFe2O4 spinel a correlated paramagnetic state resulting from the predominance of third-neighbor antiferromagnetic interactions. These interactions materialize four interlaced families of triangular planes with 120° spins emerging from the underlying pyrochlore lattice. At lower temperatures, a phase transition occurs to a noncoplanar spin structure that is characterized by six propagation vectors. This unusual multi-q order is triggered by the presence of weaker interactions up to the sixth neighbors. The system is remarkably successful in coupling the different triangular planes while maintaining their two-dimensional 120° order. Our Letter highlights the hierarchy of interactions involved in GeFe2O4, which is singular among spinel compounds since first-neighbor interactions are only a small fraction of the dominant third-neighbor ones.

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