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Tracking the Photoinduced Dynamics of a Dark Excitonic State in Single-Layer WS2 via Resonant Autler-Townes Splitting

Angela Montanaro1,2,3,*, Francesco Valiera4,5,*, Francesca Giusti1,2, Francesca Fassioli3, Chiara Trovatello6,7, Giacomo Jarc1,2,3, Enrico Maria Rigoni1,2,3, Fang Liu8,9, Xiaoyang Zhu8 et al.

Stefano Dal Conte6, Giulio Cerullo6,10, Martin Eckstein4,5, and Daniele Fausti1,2,3,†

  • *These authors contributed equally to this work.
  • †Contact author: daniele.fausti@fau.de

Phys. Rev. Lett. 136, 016902 – Published 6 January, 2026

DOI: https://doi.org/10.1103/j34b-hh1c

Abstract

Excitons in monolayer transition metal dichalcogenides (1L−TMDs) exhibit a Rydberg-like series of bound states, including optically dark levels. Using a three-pulse scheme, we directly track the dynamics of the 2p dark exciton in 1L−WS2 through the Autler-Townes splitting of the bright 1s state. The splitting, induced by a midinfrared field resonant with the 1s−2p transition, reveals distinct 1s and 2p responses to photoexcitation. This approach provides new insight into many-body effects and offers a versatile experimental framework to probe driven excitonic dynamics in quantum materials.

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