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High-Stability Single-Ion Clock with 5.5×10−19 Systematic Uncertainty

Mason C. Marshall1,*, Daniel A. Rodriguez Castillo1,2, Willa J. Arthur-Dworschack1,2, Alexander Aeppli2,3, Kyungtae Kim2,3, Dahyeon Lee2,3, William Warfield2,3, Joost Hinrichs1,4, Nicholas V. Nardelli1 et al.

Tara M. Fortier1, Jun Ye2,3, David R. Leibrandt1,2,5, and David B. Hume1,2,†

  • *Contact author: mason.marshall@nist.gov
  • †Contact author: david.hume@nist.gov

Phys. Rev. Lett. 135, 033201 – Published 14 July, 2025

DOI: https://doi.org/10.1103/hb3c-dk28

Abstract

We report a single-ion optical atomic clock with a fractional frequency uncertainty of 5.5×10−19 and fractional frequency stability of 3.5×10−16/τ/s, based on quantum logic spectroscopy of a single Al+27 ion. A cotrapped Mg+25 ion provides sympathetic cooling and quantum logic readout of the Al+27S10↔P30 clock transition. A Rabi probe duration of 1 s, enabled by laser stability transfer from a remote cryogenic silicon cavity across a 3.6 km fiber link, results in a threefold reduction in instability compared to previous Al+27 clocks. Systematic uncertainties are lower due to an improved ion trap electrical design, which reduces excess micromotion, and a new vacuum system, which reduces collisional shifts. We also perform a direction-sensitive measurement of the ac magnetic field due to the rf ion trap, eliminating systematic uncertainty due to field orientation.

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