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    Symmetry Analysis of Magnetoelectric Coupling Effect in All Point Groups

    Xinhai Tu1,2,*, Di Wang1,2,*, Hanjing Zhou1,2, Songsong Yan1,2, Huimei Liu1,2, Hongjun Xiang3, and Xiangang Wan1,2,4,5,†

    • *These authors contributed equally to this work.
    • †Contact author: xgwan@nju.edu.cn

    Phys. Rev. Lett. 136, 046802 – Published 29 January, 2026

    DOI: https://doi.org/10.1103/dzpt-kz32

    Abstract

    Symmetry analysis provides crucial insights into the magnetoelectric coupling effect in type-II multiferroics. In this Letter, we comprehensively investigate couplings between electric polarization and inhomogeneous magnetization across all 32 nonmagnetic point groups using a phenomenological Landau theory. Our theory successfully explains the ferroelectric polarizations in all known type-II multiferroics characterized by incommensurate magnetic orders. In addition, we predict 12 promising type-II multiferroic candidates with the highest magnetic transition temperature of 84 K through systematic screening of MAGNDATA database. Furthermore, we find that the collinear spin-sinusoidal texture emerges as a previously unrecognized source of ferroelectric polarization. We also demonstrate that topological ferroelectric vortex states can be induced by ferromagnetic vortex configurations in uniaxial point groups, opening a route to realizing coexisting multiple-vortex states in multiferroics.

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