Large Kohn Anomaly and Phonon Collapse Induced by Charge Density Wave in
Phys. Rev. Lett. 135, 036705 – Published 18 July, 2025
DOI: https://doi.org/10.1103/clg4-2zzb
Abstract
Using high-energy-resolution inelastic x-ray scattering, we observe anomalous softening and damping of the transverse acoustic phonon in as the system is cooled toward the charge density wave (CDW) transition temperature . The phonon exhibits a marked Kohn-type anomaly around the CDW wave vector and becomes overdamped within a finite momentum range already well above . The dispersion anomaly is consistent with potential Fermi surface nesting, which together with the extended phonon collapse indicates strong electron-phonon coupling. The transition temperature estimated from the phonon softening is markedly lower than , consistent with a primarily electronic instability rather than a phonon-driven transition. Our results establish as a prime example of a strongly correlated electron CDW system with exceptionally strong electron-phonon coupling driving phonon softening and collapse.