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    Superconductivity in Noncentrosymmetric Rhombohedral NbSe2

    Zhengxian Li1,*, Xiaoyu Shen1,*, Shaozheng Wang1, Kai Liu1, Yating Sha1, Tianyang Wang1, Feng Liu1, Qingchen Duan1, Kenji Watanabe2 et al.

    Takashi Taniguchi3, Peng Chen1, Shiyong Wang1, Ruidan Zhong1, Dong Qian1, Yufan Li4, Shengwei Jiang1, Noah F. Q. Yuan1, and Guorui Chen1,†

    • *These authors contributed equally to this work.
    • †Contact author: chenguorui@sjtu.edu.cn

    Phys. Rev. Lett. 137, 116002 – Published 10 September, 2026

    DOI: https://doi.org/10.1103/b68j-t167

    Abstract

    Crystal stacking offers a powerful yet underexplored route to engineer symmetry in layered superconductors. Here we report superconductivity in rhombohedral-stacked NbSe2 (3R−NbSe2), a noncentrosymmetric polytype in which global inversion symmetry is removed by stacking alone. Using comprehensive structural, transport, magnetic, and thermodynamic measurements, we establish superconductivity as a bulk property of the 3R phase and find that the in-plane upper critical field exceeds the Pauli paramagnetic limit, indicating the persistence of strong Ising-type spin-orbit coupling. Unlike the thickness-dependent superconductivity in centrosymmetric 2H−NbSe2, the superconducting transition temperature in 3R−NbSe2 shows little dependence on the layer number but exhibits an unusually strong sensitivity to disorder. We further observe strongly enhanced nonlinear optical and electrical responses near the superconducting transition, consistent with stacking-induced inversion-symmetry breaking. Our results identify 3R−NbSe2 as a single-phase platform in which stacking engineering reshapes superconductivity and enables nonlinear transport phenomena in layered materials.

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