Relationship between Friction and Molecular Structure: Alkylsilane Lubricant Films under Pressure

E. Barrena, S. Kopta, D. F. Ogletree, D. H. Charych, and Miquel Salmeron
Phys. Rev. Lett. 82, 2880 – Published 5 April 1999
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Abstract

We demonstrate that energy losses during friction of alkylsilane self-assembled monolayers with sharp atomic force microscope tips can be correlated to molecular events occurring at specific threshold loads. Under these loads, discrete molecular tilts occur, which are dictated by the geometrical requirements of the close packing of molecules. The barriers overcome during these tilt events give rise to discrete changes in the frictional forces.

  • Received 17 November 1998

DOI:https://doi.org/10.1103/PhysRevLett.82.2880

©1999 American Physical Society

Authors & Affiliations

E. Barrena*, S. Kopta, D. F. Ogletree, D. H. Charych, and Miquel Salmeron§

  • Materials Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720

  • *Permanent address: Instituto de Ciencia de Materiales de Madrid, CSIC, Madrid, Spain.
  • Permanent address: Institute of Physics, University of Basel, Basel, Switzerland.
  • Present address: Chiron Technologies, Emeryville, CA.
  • §To whom correspondence should be addressed.

Comments & Replies

Kopta et al. Reply:

S. Kopta, E. Barrena, D. F. Ogletree, D. H. Charych, and M. Salmeron
Phys. Rev. Lett. 83, 1697 (1999)

Comment on “Relationship between Friction and Molecular Structure: Alkylsilane Lubricant Films under Pressure”

Alois Würger
Phys. Rev. Lett. 83, 1696 (1999)

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Vol. 82, Iss. 14 — 5 April 1999

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