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    Spin exchange in elastic e-O2 collisions

    Fernando J. da Paixo and Marco A. P. Lima

    Vincent McKoy

    • Instituto de Física ‘‘Gleb Wataghin,’’ Unicamp, Caixa Postal 6165, 13081 Campinas, São Paulo, Brazil

    • Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, California 91125

    Phys. Rev. Lett. 68, 1698 – Published 16 March, 1992

    DOI: https://doi.org/10.1103/PhysRevLett.68.1698

    Abstract

    Recent experiments using polarized electron beams have shown that spin exchange effects for elastic collisions with O2 and NO are much smaller than for Na atoms. We report calculated spin-flip differential cross sections for elastic collisions of polarized electrons with O2 in agreement with experiment. In general, we can attribute the large variation of the spin-flip differential cross sections to resonances and interference effects. Such features arising from interference, however, may be washed out in the molecular case due to the average over orientations. Calculations with oriented O2 molecules show strong exchange effects as for Na.

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