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    Dynamic Slowing-Down and Nonexponential Decay of the Density Correlation Function in Dense Microemulsions

    S. H. Chen

    J. S. Huang

    • Nuclear Engineering Department, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

    • Exxon Research and Engineering Company, Clinton Township, Annandale, New Jersey 08801

    Phys. Rev. Lett. 55, 1888 – Published 28 October, 1985

    DOI: https://doi.org/10.1103/PhysRevLett.55.1888

    Abstract

    Quasielastic-light-scattering measurements were made on microemulsions in which the apparent volume fraction φ of the microemulsion droplets was varied from 0.1 to 0.75. The density correlation function shows an exponential decay at short time but deviates from it at long time especially for intermediate φ. The initial decay rates of the correlation functions decrease steadily as a function of φ, reaching a minimum at φc=0.62, and increase thereafter. The overall time dependence of the correlation functions can be fitted by the function exp[−(tT)α]; the exponent α varies from 1 down to 0.66 and back up again to 0.9 over the range of φ.

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