Icosahedral Bond Orientational Order in Supercooled Liquids

Paul J. Steinhardt, David R. Nelson, and Marco Ronchetti
Phys. Rev. Lett. 47, 1297 – Published 2 November 1981
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Abstract

Three-dimensional bond orientational order is studied via computer simulations of 864 particles interacting through a Lennard-Jones pair potential. Long-range orientational fluctuations appear upon supercooling about ten percent below the equilibrium melting temperature. The fluctuations suggest a broken icosahedral symmetry with extended correlations in the orientations of local icosahedral packing units.

  • Received 24 August 1981

DOI:https://doi.org/10.1103/PhysRevLett.47.1297

©1981 American Physical Society

Authors & Affiliations

Paul J. Steinhardt*

  • IBM Thomas J. Watson Research Laboratory, Yorktown Heights, New York 10598

David R. Nelson

  • Department of Physics, Harvard University, Cambridge, Massachusetts 02138

Marco Ronchetti

  • IBM Thomas J. Watson Research Laboratory, Yorktown Heights, New York 10598

  • *Present address: David Rittenhouse Laboratory, University of Pennsylvania, Philadelphia, Pa. 19104.
  • Present address: Dipartimento di Fisica, Libera Università degli Studi di Trento, I-38100 Trento, Italy.

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Vol. 47, Iss. 18 — 2 November 1981

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