Microelectromechanical—so-called “MEMs”—vapor cells are a key component in atom-based quantum sensors, such as clocks, gyroscopes, electric field sensors, and magnetometers. MEMs vapor cell fabrication for Rydberg atom radio frequency sensors is particularly demanding. The Rydberg states used for the sensor can shift in a constant electric field which can be generated by the internal surfaces of the vapor cell cavity. The ratio of the detection wavelength to vapor cell size can span a large range, meaning that the radio frequency field–vapor cell interaction is a critical design consideration. In many radio frequency sensing cases, there is a desire to minimize the interaction between the vapor cell and the target radio frequency field, as well as assure that every vapor cell behaves uniformly. These criteria favor MEMs vapor cells with low background electric fields. Known inert, organic coatings cannot survive the bonding temperatures required for conventional anodic bonding of a MEMs vapor cell. Applying inert, organic coatings to the internal cavities of MEMs vapor cells is a long-standing challenge. In this Letter, we present a low temperature bonding scheme that is compatible with coating the internal cavity of a MEMs vapor cell with octadecyltrichlorosilane [${\mathrm{CH}}_3({\mathrm{CH}}_2{)}_{17}{\mathrm{SiCl}}_3$, OTS]. The coating prevents the Cs used in the vapor cell from sticking to the walls. Spectral linewidths of $\sim 300\mathrm{kHz}$ are obtained using Rydberg spectroscopy, with energy shifts corresponding to electric fields $<10\mathrm{mV}{\mathrm{cm}}^{-1}$.

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• Atomic & molecular processes in external fields
• Electromagnetically induced transparency
• Laser spectroscopy
• Quantum optics
• Quantum sensing