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    Revealing Band-Hybrid Cooper Pairs on the Surface of a Superconductor with Spin-Orbit Coupling

    Javier Zaldívar1,*, Jon Ortuzar1,*, Miguel Alvarado2,3, Stefano Trivini1, Julie Baumard4, Carmen Rubio-Verdú5, Edwin Herrera6, Hermann Suderow6, Alfredo Levy Yeyati3 et al.

    F. Sebastian Bergeret4,7 and Jose Ignacio Pascual1,8,†

    • *These authors contributed equally to this work.
    • †Contact author: ji.pascual@nanogune.eu

    Phys. Rev. Lett. 135, 136201 – Published 23 September, 2025

    DOI: https://doi.org/10.1103/6jfy-cv89

    Abstract

    Most superconductors exhibit spin-singlet pairing within a single band. In multiband systems with strong spin-orbit coupling, more exotic scenarios can emerge, including Cooper pairs between bands with distinct symmetries. Here, we present evidence of the formation of Cooper pairs between spin-nondegenerate helical surface bands in the superconductor β−Bi2Pd. Scanning tunneling microscopy reveals anisotropic Yu-Shiba-Rusinov (YSR) resonances induced by vanadium impurities, with long-range amplitude modulations attributed to spin-conserving Bogoliubov quasiparticle interference (BQPI). Analysis of BQPI at the subgap YSR energy shows that only a selective subset of normal-state scattering processes contributes to Cooper pair formation, indicating interband mixing. We trace this selectivity to the hybridization of a helical surface band with others via the impurity.

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