Revealing Band-Hybrid Cooper Pairs on the Surface of a Superconductor with Spin-Orbit Coupling
Phys. Rev. Lett. 135, 136201 – Published 23 September, 2025
DOI: https://doi.org/10.1103/6jfy-cv89
Abstract
Most superconductors exhibit spin-singlet pairing within a single band. In multiband systems with strong spin-orbit coupling, more exotic scenarios can emerge, including Cooper pairs between bands with distinct symmetries. Here, we present evidence of the formation of Cooper pairs between spin-nondegenerate helical surface bands in the superconductor . Scanning tunneling microscopy reveals anisotropic Yu-Shiba-Rusinov (YSR) resonances induced by vanadium impurities, with long-range amplitude modulations attributed to spin-conserving Bogoliubov quasiparticle interference (BQPI). Analysis of BQPI at the subgap YSR energy shows that only a selective subset of normal-state scattering processes contributes to Cooper pair formation, indicating interband mixing. We trace this selectivity to the hybridization of a helical surface band with others via the impurity.