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    Direct Observation of the Surface Superconducting Gap in the Topological Superconductor Candidate β−PdBi2

    Akifumi Mine1, Takeshi Suzuki1,*,†, Yigui Zhong1, Sahand Najafzadeh1, Kenjiro Okawa2,‡, Masato Sakano3,4,§, Kyoko Ishizaka3,4,5, Shik Shin1,6,7, Takao Sasagawa2,8 et al.

    Kozo Okazaki1,7,9,∥

    • *Contact author: suzuki.takeshi.fbs@osaka-u.ac.jp
    • †Present address: Graduate School of Frontier Biosciences, The University of Osaka, 1-3 Yamadaoka, Suita, Osaka 565-0871, Japan.
    • ‡Present address: National Metrology Institute of Japan, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8563, Japan.
    • §Present address: Graduate School of Informatics and Engineering, The University of Electro-Communications, Chofu, Tokyo 182-8585, Japan.
    • ∥Contact author: okazaki@issp.u-tokyo.ac.jp

    Phys. Rev. Lett. 135, 236002 – Published 1 December, 2025

    DOI: https://doi.org/10.1103/3jgn-22rx

    Abstract

    β−PdBi2 is one of the candidates for topological superconductors with a superconducting (SC) transition temperature (Tc) of 5.3 K, in which parity mixing of a spin singlet and spin triplet has been anticipated, being crucial for the further understanding of the relationship with inversion symmetry and parity mixing in the superconductivity. In this Letter, we measured the SC gap in a high-quality single crystal of β−PdBi2 by using high-resolution laser angle-resolved photoemission spectroscopy below Tc. We found the isotropic SC gaps in momentum space for multiple bands, and observed that the difference between the SC gap of the topological surface bands and the bulk bands is about 0.1 meV, consistent with other experimental results. These direct and quantitative experimental results support the possibility of β−PdBi2 as a topological superconductor, characterized by unique crystal and electronic band structures.

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