Export citation

Export citation

Choose format for download:

Download Citation

    Many-Body Correlation Effects in Fröhlich Electron-Phonon Coupling

    Zien Zhu1, Chih-En Hsu1,2, Benran Zhang1, Zhenfa Zheng1, Mauro Del Ben3, Antonios M. Alvertis4,5, Hung-Chung Hsueh2, and Zhenglu Li1,*

    • *Contact author: zhenglul@usc.edu

    Phys. Rev. Lett. 137, 146401 – Published 30 September, 2026

    DOI: https://doi.org/10.1103/2r8c-qw21

    Abstract

    In compound semiconductors and insulators, the polar electron-phonon coupling diverges at long range, known as the Fröhlich interaction. Modern first-principles electron-phonon calculations treat the Fröhlich interaction in a semiclassical electrostatic formalism based on density-functional perturbation theory. Here, using many-body GW perturbation theory, we reveal important electron correlation effects in the Fröhlich-type electron-phonon coupling, which are missed by the prevailing approaches and rooted in the fundamentally distinct behavior between quasiparticle self-energy and semilocal exchange-correlation functionals in the long-range limit. Going beyond the electrostatic treatment, we derive and implement the GW self-energy contribution to the long-range polar electron-phonon coupling, and demonstrate its critical role and nontrivial behaviors in properties such as electron linewidth and polaron formation in several prototype semiconductors. Remarkably, calculations on photoemission kink in electron-doped TiO2 achieve excellent agreement with experiment. Our work establishes the many-body generalization of the Fröhlich interaction that is essential for accurate electron-phonon calculations at the full GW level combined with Wannier interpolation techniques.

    Physics Subject Headings (PhySH)

    Authorization Required

    We need you to provide your credentials before accessing this content.

    Supplemental Material (Subscription Required)

    References (Subscription Required)

    Outline

    Information

    Sign In to Your Journals Account

    Filter

    Filter

    Article Lookup

    Enter a citation