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Forces between elongated particles in a nematic colloid

D. Andrienko, M. Tasinkevych, P. Patrício, M. P. Allen, and M. M. Telo da Gama
Phys. Rev. E 68, 051702 – Published 3 November 2003
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Abstract

Using molecular dynamics simulations we study the interactions between elongated colloidal particles (length to breath ratio 1) in a nematic host. The simulation results are compared to the results of a Landau–de Gennes elastic free energy. We find that depletion forces dominate for the sizes of the colloidal particles studied. The tangential component of the force, however, allows us to resolve the elastic contribution to the total interaction. We find that this contribution differs from the quadrupolar interaction predicted at large separations. The difference is due to the presence of nonlinear effects, namely, the change in the positions and structure of the defects and their annihilation at small separations.

  • Received 10 July 2003

DOI:https://doi.org/10.1103/PhysRevE.68.051702

©2003 American Physical Society

Authors & Affiliations

D. Andrienko1, M. Tasinkevych2, P. Patrício2,3, M. P. Allen4, and M. M. Telo da Gama2

  • 1Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany
  • 2Departamento de Física da Faculdade de Ciências and Centro de Física Teóretica e Computacional, Univercidade de Lisboa, Avenida Professor Gama Pinto 2, P-1649-003 Lisboa Codex, Portugal
  • 3Instituto Superior de Engenharia de Lisboa, Rua Conselheiro Emídio Navarro 1, P-1949-014 Lisboa, Portugal
  • 4Center for Scientific Computing, University of Warwick, Coventry, United Kingdom

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Vol. 68, Iss. 5 — November 2003

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