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    Empty electronic states of silver as measured by inverse photoemission

    B. Reihl and R. R. Schlittler

    • IBM Zurich Research Laboratory, CH-8803 Rüschlikon, Switzerland

    Phys. Rev. B 29, 2267 – Published 15 February, 1984

    DOI: https://doi.org/10.1103/PhysRevB.29.2267

    Abstract

    We have performed inverse photoemission (bremsstrahlung isochromat spectroscopy) at hν=9.7 eV on polycrystalline silver. Our spectrum can be related to the calculated density of unoccupied states up to 7 eV above the Fermi level EF. Pronounced features in the isochromat spectrum are associated with critical points in the band structure of silver. We find X6 at EF+(2.1±0.1) eV and L4+ at EF+(3.77±0.09) eV. The results are compared with band-structure calculations as well as other experimental findings.

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