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    Experimental bulk energy bands for diamond using hν-dependent photoemission

    F. J. Himpsel, J. F. van der Veen, and D. E. Eastman

    • IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598

    Phys. Rev. B 22, 1967 – Published 15 August, 1980

    DOI: https://doi.org/10.1103/PhysRevB.22.1967

    Abstract

    Using photon-energy-dependent photoemission techniques with a diamond (111)-(1 × 1) crystal surface, we have determined critical points of energy bands at Γ and L (Γ1=21 eV, L1=12.8 eV, L2=15.2 eV, Γ15=+6.0 eV, Γ2=+15.3 eV, L2=+20 eV, Γ=+24 eV with respect to the top of the valence band Γ25). Recent ab initio calculations agree with our results within 0.6 eV for the valence bands and show qualitative agreement for the empty conduction bands. The final bands are observed to be non-free-electron-like up to at least + 30 eV.

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