Experimental bulk energy bands for diamond using -dependent photoemission
Phys. Rev. B 22, 1967 – Published 15 August, 1980
DOI: https://doi.org/10.1103/PhysRevB.22.1967
Abstract
Using photon-energy-dependent photoemission techniques with a diamond (111)-(1 × 1) crystal surface, we have determined critical points of energy bands at and ( eV, eV, eV, eV, eV, eV, eV with respect to the top of the valence band ). Recent ab initio calculations agree with our results within 0.6 eV for the valence bands and show qualitative agreement for the empty conduction bands. The final bands are observed to be non-free-electron-like up to at least + 30 eV.