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Emission properties of a hybrid metallized diamond(001) photocathode
Phys. Rev. Accel. Beams 28, 123401 – Published 4 December, 2025
DOI: https://doi.org/10.1103/j1d9-bwdr
Abstract
The spectral emission characteristics of a proof-of-concept hybrid metallized diamond(001) photocathode are presented. The quantum efficiency (QE) is shown to be determined by the photoinjection efficiency across the ohmic contact at the back metallized face, whereas the mean transverse energy (MTE) of the photoemitted electrons is consistent with an (optical)phonon-assisted and momentum-resonant Franck-Condon mechanism [Franck-Condon electron emission from polar semiconductor photocathodes, Phys. Rev. Appl. 23, 054065 (2025)] following electron drift transport to the untreated diamond(001) front emission face. Emission is observed from both the lower and upper conduction bands of diamond with positive and negative electron affinity, respectively. A potential route to the realization of a red-visible photocathode based on this concept with a sub-50 meV MTE and a QE greater than 0.1% is discussed.
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References (95)
- D. H. Dowell, I. Bazarov, B. Dunham, K. Harkey, C. Hernandez-Garcia, R. Legg, H. Padmore, T. Rao, J. Smedley, and W. Wan, Cathode R&D for future light sources, Nucl. Instrum. Methods Phys. Res., Sect. A 622, 685 (2010).
- R. Xiang and J. Schaber, Review of recent progress on advanced photocathodes for superconducting rf gun, Micromachines 13, 1241 (2022).
- P. Michelato, Photocathodes for rf photoinjector, Nucl. Instrum. Methods Phys. Res., Sect. A 393, 455 (1997).
- P. Musumeci, J. Giner Navarro, J. B. Rosenzweig, L. Cultrera, I. Bazarov, J. Maxson, S. Karkare, and H. Padmore, Advances in bright electron sources, Nucl. Instrum. Methods Phys. Res., Sect. A 907, 209 (2018).
- P. Emma et al., First lasing and operation of an ångstrom-wavelength free electron laser, Nat. Photonics 4, 641 (2010).
- H. N. Chapman et al., Femtosecond diffractive imaging with a soft-x-ray free-electron laser, Nat. Phys. 2, 839 (2006).
- G. Sciani and R. J. D. Miller, Femtosecond electron diffraction: Heralding the era of atomically resolved dynamics, Rep. Prog. Phys. 74, 096101 (2005).
- J. Hastings, F. Rudakov, D. Dowell, J. Schmerge, J. Cardoza, J. Castro, S. Gierman, H. Loos, and P. M. Weber, Ultrafast time-resolved electron diffraction with megavolt electron beams, Appl. Phys. Lett. 89, 184109 (2006).
- R. Li, C. Tang, Y. Du, W. Huang, Q. Du, J. Shi, L. Yan, and X. Wang, Experimental demonstration of high quality MeV ultrafast electron diffraction, Rev. Sci. Instrum. 80, 083303 (2009).
- P. Musumeci, J. Moody, C. Scoby, M. Gutierrez, H. Bender, and N. Wilcox, High quality single shot diffraction patterns using ultrashort megaelectron volt beams from a radio frequency photoinjector, Rev. Sci. Instrum. 81, 013306 (2010).
- S. Weathersby et al., Mega-electron-volt ultrafast electron diffraction at SLAC National Accelerator Laboratory, Rev. Sci. Instrum. 86, 073702 (2015).
- T. LaGrange, M. R. Armstrong, K. Boyden, C. G. Brown, G. H. Campbell, J. D. Colvin, W. J. DeHope, A. M. Frank, D. J. Gibson, F. V. Hartemann, J. S. Kim, W. E. King, B. J. Pyke, B. W. Reed, M. D. Shirk, R. M. Shuttlesworth, B. C. Stuart, B. R. Torralva, and N. D. Browning, Single-shot dynamic transmission electron microscopy, Appl. Phys. Lett. 89, 044105 (2006).
- Y. Murooka, N. Naruse, S. Sakakihara, M. Ishimaru, J. Yang, and K. Tanimura, Transmission-electron diffraction by MeV electron pulses, Appl. Phys. Lett. 98, 251903 (2011).
- R. K. Li and P. Musumeci, Single-shot MeV transmission electron microscopy with picosecond temporal resolution, Phys. Rev. Appl. 2, 1 (2014).
- S. Quan, J. Hao, L. Lin, F. Zhu, F. Wang, L. Feng, S. Huang, Z. Wang, X. Wen, P. Fan, H. Xie, K. Liu, K. Zhao, and J. Chen, Stable operation of the DC-SRF photoinjector, Nucl. Instrum. Methods Phys. Res., Sect. A 798, 117 (2015).
- N. Terunuma, A. Murata, M. Fukuda, K. Hirano, Y. Kamiya, T. Kii, M. Kuriki, R. Kuroda, H. Ohgaki, K. Sakaue, M. Takano, T. Takatomi, J. Urakawa, M. Washio, Y. Yamazaki, and J. Yang, Improvement of an S-band rf gun with a photocathode for the KEK-ATF, Nucl. Instrum. Methods Phys. Res., Sect. A 613, 1 (2010).
- E. Prat, S. Bettoni, H.-H. Braun, R. Ganter, and T. Schietinger, Measurements of copper and cesium telluride cathodes in a radio-frequency photoinjector, Phys. Rev. ST Accel. Beams 18, 043401 (2015).
- F. Zhou, C. Adolphsen, A. Benwell, G. Brown, D. H. Dowell, M. Dunning, S. Gilevich, K. Grouev, G. Huang, B. Jacobson, X. H. Liu, A. Miahnahri, F. Sannibale, J. Schmeger, and T. Vecchione, Commissioning of the SLAC Linac Coherent Light Source II electron source, Phys. Rev. Accel. Beams 24, 073401 (2021).
- W. Spicer, Photoemissive, photoconductive, and optical absorption studies of alkali-antimony compounds, Phys. Rev. 112, 114 (1958).
- L. Cultrera, I. Bazarov, A. Bartnik, B. Dunham, S. Karkare, R. Merluzzi, and M. Nichols, Thermal emittance and response time of a cesium antimonide photocathode, Appl. Phys. Lett. 99, 152110 (2011).
- L. Cultrera, S. Karkare, H. Lee, X. Liu, I. Bazarov, and B. Dunham, Cold electron beams from cryocooled, alkali antimonide photocathodes, Phys. Rev. ST Accel. Beams 18, 113401 (2015).
- A. Galdi, J. Balajka, W. DeBenedetti, L. Cultrera, I. V. Bazarov, M. Hines, and J. M. Maxson, Reduction of surface roughness emittance of photocathodes grown via codepositionon on single crystal substrates, Appl. Phys. Lett. 118, 244101 (2021).
- C. T. Parzyck, A. Galdi, J. K. Nangoi, W. J. I. DeBenedetti, J. Balajka, B. D. Faeth, H. Paik, C. Hu, T. A. Arias, M. A. Hines, D. G. Schlom, K. M. Shen, and J. M. Maxson, Single-crystal alkali antimonide photocathodes: High efficiency in the ultrathin limit, Phys. Rev. Lett. 128, 114801 (2022).
- D. H. Dowell, K. J. Davis, K. D. Friddell, E. L. Tyson, C. A. Lancaster, L. Milliman, R. E. Rodenburg, T. Aas, M. Bemes, S. Z. Bethel, P. E. Johnson, K. Murphy, C. Whelen, G. E. Busch, and D. K. Remelius, First operation of a photocathode radio frequency gun injector at high duty factor, Appl. Phys. Lett. 63, 2035 (1993).
- T. Vecchione, I. Ben-Zvi, D. H. Dowell, J. Feng, T. Rao, J. Smedley, W. Wan, and H. Padmore, A low emittance and high efficiency visible light photocathode for high brightness accelerator-based x-ray light sources, Appl. Phys. Lett. 99, 034103 (2011).
- E. Wang, V. N. Litvinenko, I. Pinayev, M. Gaowei, J. Skaritka, S. Belomestnykh, I. Ben-Zvi, J. C. Brutus, Y. Jing, J. Biswas, J. Ma, G. Narayan, I. Petrushina, O. Rahman, T. Xin, T. Rao, F. Severino, K. Shih, K. Smith, G. Wang, and Y. Wu, Long lifetime of bialkali photocathodes operating in high gradient superconducting radio frequency gun, Sci. Rep. 11, 4477 (2021).
- I. Bazarov, L. Cultrera, A. Bartnik, B. Dunham, S. Karkare, Y. Li, X. Liu, J. Maxson, and W. Roussel, Thermal emittance measurements of a cesium potassium antimonide photocathode, Appl. Phys. Lett. 98, 224101 (2011).
- J. Maxson, L. Cultrera, C. Gulliford, and I. Bazarov, Measurement of the tradeoff between intrinsic emittance and quantum efficiency from a NaKSb photocathode near threshold, Appl. Phys. Lett. 106, 234102 (2015).
- W. Spicer, Negative affinity 3–5 photocathodes: Their physics and technology, Appl. Phys. 12, 115 (1977).
- D. Pierce and F. Meier, Photoemission of spin-polarized electrons from GaAs, Phys. Rev. B 13, 5484 (1976).
- J. Kirschner, H. P. Oepen, and H. Ibach, Energy- and spin-analysis of polarized photoelectrons from NEA GaAs, Appl. Phys. A 30, 177 (1983).
- I. Bazarov, B. M. Dunham, Y. Li, X. Liu, D. Ouzounov, C. Sinclair, F. Hannon, and T. Miyajima, Thermal emittance and response time measurements of negative electron affinity photocahtodes, J. Appl. Phys. 103, 054901 (2008).
- S. Uchiyama, Y. Takagi, M. Niigaki, H. Kan, and H. Kondoh, GaN-based photocathodes with extremely high quantum efficiency, Appl. Phys. Lett. 86, 103511 (2005).
- I. Bazarov, B. Dunham, X. Liu, M. Virgo, M. Dadiran, F. Hannon, and H. Sayed, Thermal emittance and response time measurements of a GaN photocathode, J. Appl. Phys. 105, 083715 (2009).
- S. Levenson, M. Andorf, B. Dickensheets, I. Bazarov, A. Galdi, J. Encomendero, V. Protasenko, D. Jena, H. Xing, and J. M. Maxson, Measurement of spin-polarized photoemission from wurtzite and zinc blende gallium nitride photocathodes, Appl. Phys. Lett. 125, 034107 (2024).
- N. Chanlek, J. Herbert, R. Jones, L. Jones, K. Middleman, and B. L. Militsyn, The degradation of quantum efficiency in negative electron affinity GaAs photocathodes under gas pressure, Appl. Phys. 47, 055110 (2014).
- L. Jones, H. Scheibler, S. Kosolobov, A. Terekhov, B. Militsyn, and T. Noakes, Non-monotonic behaviour in the mean transverse energy of electrons emitted from a reflection-mode p-GaAs(Cs,O) photocathode during its QE degradation through oxygen exposure, J. Phys. D 54, 205301 (2021).
- L. Angeloni, S. Baryshev, M. Mühle, and W. A. Schroeder, Spectral emission properties of a nitrogen-doped diamond(001) photocathode: Hot electron transport and transverse momentum filtering, Phys. Rev. B 107, 165105 (2023).
- J. D. Rameau, J. Smedley, E. M. Muller, T. E. Kidd, and P. D. Johnson, Properties of hydrogen terminated diamond as a photocathode, Phys. Rev. Lett. 106, 137602 (2011): This work gives an effective Fröhlich coupling constant for the LCB of diamond with an effective mass of in the (001) emission direction, so that the intrinsic Fröhlich coupling constant .
- L. A. Angeloni, I-J. Shan, J. H. Leach, and W. A. Schroeder, Iron dopant energy levels in , Appl. Phys. Lett. 124, 252104 (2024).
- H. Hoff, G. Waytena, C. Vold, J. Suehle, I. Isaacson, M. Rebbert, D. Ma, and K. Harris, Ohmic contacts to semiconducting diamond using trilayer metallization scheme, Diamond Relat. Mater. 5, 1450 (1996).
- Yuan Liu, Recent research on ohmic contacts on GaN-based materials, IOP Conf. Ser. 738, 012007 (2020).
- L. A. M. Lyle, Critical review of Ohmic and Schottky contacts to , J. Vac. Sci. Technol. A 40, 060802 (2022).
- O. Sadowski, M. Kaminski, A. Taube, J Tarenko, M. Guiziewicz, M. Wzorek, J. Maleszyk, I. Jozwik, A. Szerling, P. Prystawko, M. Bockowski, and I. Grzegory, Low-resistivity Ohmic contacts to Ga- and N-face n-GaN for vertical power devices, Phys. Status Solidi A 221, 2400076 (2024).
- S. Karkare, D. Dimitrov, W. Schaff, L. Cultrera, A. Bartnik, X. Liu, E. Sawyer, T. Esposito, and I. Bazarov, Monte Carlo charge transport and photoemission from negative electron affinity GaAs photocathodes, J. Appl. Phys. 113, 104904 (2013); 117, 109901(E) (2015).
- J. Marini, L. Bell, and F. Shahedipour-Sandvik, Monte Carlo simulation of III-nitride photocathodes, J. Appl. Phys. 123, 124502 (2018).
- W. A. Schroeder, L. A. Angeloni, I-J. Shan, and L. B. Jones, Franck-Condon electron emission from polar semiconductor photocathodes, Phys. Rev. Appl. 23, 054065 (2025).
- M. Liao, Y. Koide, and J. Alvarez, Thermally stable visible-blind diamond photodiode using tungsten carbide Schottky contact, Appl. Phys. Lett. 87, 022105 (2005).
- V. A. Kukushkin, M. A. Lobaev, S. A. Bogdanov, A. N. Stepanov, S. A. Kraev, A. I. Okhapkin, E. A. Arkhipova, A. V. Zdoroveyshchev, and M. V. Ved, Visible and near-infrared photodetector on chemically vapor deposited diamond, Diamond Relat. Mater. 97, 107444 (2019).
- W. Pötz and P. Vogl, Theory of optical-phonon deformation potentials in tetrahedral semiconductors, Phys. Rev. B 24, 2025 (1981).
- USA Applied Diamond Inc., http://www.usapplieddiamond.com.
- E. Rohrer, C. F. O. Graeff, R. Janssen, C. E. Nebel, M. Stutzmann, H. Güttler, and R. Zachai, Nitrogen-related dopant and defect states in CVD diamond, Phys. Rev. B 54, 7874 (1996).
- J. Rosa, M. Vaněček, M. Nesládek, and L. M. Stals, Photoionization cross-section of dominant defects in CVD diamond, Diam. Relat. Mater. 8, 721 (1999).
- S. Karkare and I. Bazarov, Effects of surface nonuniformities on the mean transverse energy from photocathodes, Phys. Rev. Appl. 4, 024015 (2015).
- Z. Zhang and C. Tang, Analytical study on emittance growth caused by roughness of a metallic photocathode, Phys. Rev. ST Accel. Beams 18, 053401 (2015).
- G. Adhikari, P. Riley, and W. A. Schroeder, Spectral characterization of a Rh(110) photocathode: Band structure interpretation, AIP Adv. 9, 065305 (2019).
- L. Angeloni, I.-J. Shan, and W. A. Schroeder, Sub-threshold ultrafast one-photon photoemission from a Cu(111) photocathode, AIP Adv. 12, 105129 (2022).
- J. I. Dadap, G. B. Focht, D. H. Reitze, and M. C. Downer, Two-photon absorption in diamond and its application to ultraviolet femtosecond pulse-width measurement, Opt. Lett. 16, 499 (1991).
- D. C. Clark, P. J. Dean, and P. V. Harris, Intrinsic absorption edge in diamond, Proc. R. Soc. A 277, 312 (1964).
- H. Löfås, A. Grigoriev, J. Isberg, and R. Ahuja, Effective masses and electronic structure of diamond including electron correlation effects in first principles calculations using the GW-approximation, AIP Adv. 1, 032139 (2011).
- K. Seeger, Semiconductor physics—An introduction, Springer Series in Solid-State Sciences (Springer Verlag, Berlin, 1989), Vol. 40.
- L. G. Groves and A. E. Martin, The dielectric constant of diamond, Trans. Faraday Soc. 35, 575 (1940).
- C. J. H. Wort and R. S. Balmer, Diamond as an electronic material, Mater. Today 11, 22 (2008).
- F. Nava, C. Canali, C. Jacobine, L. Reggiani, and S. F. Kozlov, Electron effective masses and lattice scattering in natural diamond, Solid State Commun. 33, 475 (1980).
- J. Lee, C. Bayram, and J.-P. Leburton, High field transport in (ultra) wide bandgap semiconductors: Diamond versus cubic GaN, IEEE Trans. Electron Devices 71, 5638 (2024).
- K. Ishioka, M. Hase, and M. Kitajima, Coherent optical phonons in diamond, Appl. Phys. Lett. 89, 231916 (2006).
- F. Giustino, S. G. Louie, and M. L. Cohen, Electron-phonon renormalization of the direct band gap of diamond, Phys. Rev. Lett. 105, 265501 (2010).
- L. Diederich, O. M. Küttel, P. Aebi, and L. Schlapbach, Electron affinity and work function of differently oriented and doped diamond surfaces determined by photoelectron spectroscopy, Surf. Sci. 418, 219 (1998).
- M. J. Rutter and J. Robertson, Ab initio calculation of electron affinities of diamond surfaces, Phys. Rev. B 57, 9241 (1998).
- J. T. Devreese, Polarons in Encyclopedia of Applied Physics (Wiley-VCH Publishers Inc., Weinheim, 1996), Vol. 14, pp. 383–409.
- M. E. Mora-Ramos, F. J. Rodriguez, and L. Quiroga, Polarons in wurtzite nitride semiconductors, Solid State Commun. 109, 767 (1999).
- G. D. Mahan, Many-Particle Physics, 2nd ed. (Plenum Press, New York, 1990).
- K. Ishizaka, R. Eguchi, S. Tsuda, A. Chainani, T. Yokoya, T. Kiss, T. Shimojima, T. Togashi, S. Watanabe, C.-T. Chen, Y. Takano, M. Nagao, I. Sakaguchi, T. Takenouchi, H. Kawarada, and S. Shin, Temperature-dependent localized excitations of doped carriers in superconducting diamond, Phys. Rev. Lett. 100, 166402 (2008).
- N. Tandon, J. D. Albrecht, and L. R. Ram-Mohan, Electron-phonon coupling and associated scattering rate in diamond, Diamond Relat. Mater. 56, 1 (2015).
- Y. Katamune, A. Izumi, K. Ichikawa, and S. Koizumi, Heavy phosphorous doping of diamond by hot-filament chemical vapor deposition, Diamond Relat. Mater. 134, 109789 (2023).
- J. van der Weide, Z. Zhang, P. K. Baumann, M. G. Wensell, J. Bernholc, and R. J. Nemanich, Negative-electron-affinity effects on the diamond (100) surface, Phys. Rev. B 50, 5803 (1994).
- X. Chang, Q. Wu, I. Ben-Zvi, A. Burrill, J. Kewisch, T. Rao, J. Smedley, E. Wang, E. M. Muller, R. Busby, and D. Dimitrov, Electron beam emission from a diamond-amplifier cathode, Phys. Rev. Lett. 105, 164801 (2010).
- F. Zhou, C. Adolphsen, D. Dowell, and R. Xiang, Overview of CW electron guns and LCLS-II RF gun performance, Front. Phys. 11, 1150809 (2023).
- W. Götz, N. M. Johnson, C. Chen, H. Liu, C. Kuo, and W. Imler, Activation energies of Si donors in GaN, Appl. Phys. Lett. 68, 3144 (1996).
- Jiaye Zhang, Jueli Shi, Dong-Chen Qi, Lang Chen, and K. H. L. Zhang, Recent progress on the electronic structure, defect, and doping properties of , APL Mater. 8, 020906 (2020).
- V. Yu. Davydov, Yu. E. Kitaev, I. N. Goncharuk, A. N. Smirnov, J. Graul, O. Semchnova, D. Uffmann, M. B. Smirnov, A. P. Mirgorodsky, and R. A. Evarestov, Phonon dispersion and Raman scattering in hexagonal GaN and AlN, Phys. Rev. B 58, 12899 (1998).
- B. M. Jensen, R. Gillen, Z. Galazka, J. Maultzsch, and M. R. Wagner, First- and second-order Raman spectroscopy of monoclinic , Phys. Rev. Mater. 6, 054601 (2022).
- I. Vurgaftman and J. R. Meyer, Band parameters for nitrogen-containing semiconductors, J. Appl. Phys. 94, 3675 (2003).
- W. Schroeder and G. Adhikari, Evaluation of photocathode emission properties in an electron gun: One-step photoemission from bulk-band to vacuum states, New J. Phys. 21, 033040 (2019).
- A. Udabe, I. Baraia-Etxaburu, and D. G. Diez, Gallium nitride power devices: A state of the art review, IEEE Access 11, 48627 (2023).
- K. Németh, K. C. Harkay, M. van Veenendaal, L. Spentzouris, M. White, K. Attenkofer, and G. Srajer, High-brightness photocathodes through ultrathin surface layers on metals, Phys. Rev. Lett. 104, 046801 (2001).
- W. He, S. Vilayurganapathy, A. G. Joly, T. C. Droubay, S. A. Chambers, J. R. Maldonado, and W. P. Hess, Comparison of CsBr and KBr coated Cu photocathodes: Effects of laser irradiation and work function changes, Appl. Phys. Lett. 102, 071604 (2013).
- L. Kong, A. G. Joly, T. C. Droubay, Y. Gong, and W. P. Hess, Enhanced quantum efficiency from hybrid cesium halide/copper photocathodes, Appl. Phys. Lett. 104, 171106 (2014).
- J. Droubay, L. Kong, S. A. Chambers, and W. P. Hess, Work function reduction by BaO: Growth of crystalline barium oxide on Ag(001) and Ag(111) surfaces, Surf. Sci. 632, 201 (2015).
- T. C. Droubay, S. A. Chambers, A. G. Joly, W. P. Hess, K. Németh, K. C. Harkay, and L. Spentzouris, Metal-insulator photocathode heterojunction for directed electron emission, Phys. Rev. Lett. 112, 067601 (2014).
- L. Kong, A. G. joly, T. C. Droubay, and W. P. Hess, Quantum efficiency enhancement in CsI/metal photocathodes, Chem. Phys. Lett. 621, 155 (2015).
- C. Benjamin, H. M. Chum, T. J. Rehaag, L. A. J. Soomary, C. P. Welsch, L. B. Jones, T. C. Q. Noakes, and G. R. Bell, Enhanced performance of an Ag(100) photocathode by an ultra-thin MgO film, J. Appl. Phys. 132, 195303 (2022).
- J. K. Bae, L. Cultrera, P. DiGiacomo, and I. Bazarov, Rugged spin-polarized electron sources based on negative electron affinity GaAs photocathode with robust coating, Appl. Phys. Lett. 112, 154101 (2018).
- C. Franchini, M. Reticcioli, M. Setvin, and U. Diebold, Polarons in materials, Nat. Rev. Mater. 6, 560 (2021).
- L. A. Angeloni, W. A. Schroeder, and I.-J. Shan, Metallized diamond photocathode data (2023), 10.25417/uic.29319296.v1.