• Accepted Paper

Fully relativistic calculation of thermal shifts in the spectra of the hydrogen molecular ion

M. A. Reiter, A. A. Anikin, A. A. Kotov, D. A. Glazov, T. A. Zalialiutdinov, and D. A. Solovyev

Phys. Rev. A - Accepted 29 October, 2026

DOI: https://doi.org/10.1103/fwr7-9n6v

Abstract

Within a fully relativistic framework, we discuss the one‑loop self‑energy correction, generalized to the presence of external blackbody radiation, for a bound electron in the hydrogen molecular ion. The calculations rely on the thermal part of the photon propagator from finite-temperature quantum electrodynamics. The ADKB method, which extends the dual kinetic balance condition to axially symmetric systems, is adopted together with a B-spline-based trial function. The results are obtained within the Born–Oppenheimer adiabatic approximation. Thermal shift for the ground term of the hydrogen molecular ion is computed as a function of the internuclear distance. Including this correction, we present the resulting shifts of the vibrational levels. The analysis focuses on the dynamical effect, a comparison is made with data available in the current literature.

Export citation

Export citation

Choose format for download:

Download Citation

If the author has provided any supplemental materials with this article they will be available upon publication of the version of record.

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation