Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Quantum computing demonstration of the polaron-molecule transition on a noisy intermediate-scale quantum device

Hugo Catalá1,2,*, Ezequiel Valero1,3, and Germán Rodrigo2

  • *Contact author: hugo.catala@ific.uv.es

Phys. Rev. A 114, 032609 – Published 11 September, 2026

DOI: https://doi.org/10.1103/2kdj-6pdz

Abstract

The simulation of strongly correlated fermionic systems remains a significant challenge in computational physics due to the exponential growth of the Hilbert space and the fermionic sign problem. In this work, we report a quantum computing demonstration exploring the unified physics of the Fermi polaron and the Bose-Einstein condensate to Bardeen-Cooper-Schrieffer crossover. We develop an effective Hamiltonian formalism that bridges pairing superfluidity and impurity physics, mapping the system onto a gate-based quantum processor via the Jordan-Wigner transformation. By utilizing a first-order Trotter-Suzuki decomposition, we implement an ancilla-controlled Ramsey interferometry protocol to resolve the system's spectral response. Our implementation captures the smooth transition from a dressed quasiparticle (polaron) regime to a stable molecular bound state, characterized by a linear energy renormalization in the strong-coupling limit. We benchmark the quantum protocol against exact diagonalization and demonstrate its execution on the Barcelona Supercomputing Center quantum hardware. To ensure reproducibility, we provide comprehensive device calibration metrics, including qubit coherence times and gate fidelities at the time of execution. Despite inherent hardware noise, the hybrid variational approach qualitatively observes the bifurcation of the spectral density.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (40)

  1. W. Zwerger, The BCS-BEC Crossover and the Unitary Fermi Gas (Springer, Berlin, 2012).
  2. S. Giorgini, L. P. Pitaevskii, and S. Stringari, Theory of ultracold atomic Fermi gases, Rev. Mod. Phys. 80, 1215 (2008).
  3. P. Nozières and S. Schmitt-Rink, Bose condensation in an attractive fermion gas: From weak to strong coupling superconductivity, J. Low Temp. Phys. 59, 195 (1985).
  4. C. Chin, R. Grimm, P. S. Julienne, and E. Tiesinga, Feshbach resonances in ultracold gases, Rev. Mod. Phys. 82, 1225 (2010).
  5. A. J. Leggett, Quantum Liquids: Bose Condensation and Cooper Pairing in Condensed-Matter Systems, (Oxford University Press, Oxford, 2006).
  6. D. M. Eagles, Possible pairing without superconductivity at low carrier concentrations in bulk and thin-film superconducting semiconductors, Phys. Rev. 186, 456 (1969).
  7. P. Massignan, M. Zaccanti, and G. M. Bruun, Polarons, dressed molecules and itinerant ferromagnetism in ultracold Fermi gases, Rep. Prog. Phys. 77, 034401 (2014).
  8. B. Nachman, M. Urbanek, W. A. de Jong, and C. W. Bauer, Unfolding quantum computer readout noise, npj Quantum Inf. 6, 84 (2020).
  9. K. Temme, S. Bravyi, and J. M. Gambetta, Error mitigation for short-depth quantum circuits, Phys. Rev. Lett. 119, 180509 (2017).
  10. M. Reiher, N. Wiebe, K. M. Svore, D. Wecker, and M. Troyer, Elucidating reaction mechanisms on quantum computers, Proc. Natl. Acad. Sci. USA 114, 7555 (2017).
  11. C. Cade, L. Mineh, A. Montanaro, and S. Stanisic, Strategies for solving the Fermi-Hubbard model on near-term quantum computers, Phys. Rev. B 102, 235122 (2020).
  12. C. J. Pethick and H. Smith, Bose-Einstein Condensation in Dilute Gases, 2nd ed. (Cambridge University Press, Cambridge, 2008).
  13. C. A. Regal, M. Greiner, and D. S. Jin, Observation of resonance condensation of fermionic atom pairs, Phys. Rev. Lett. 92, 040403 (2004).
  14. J. Wang, X.-J. Liu, and H. Hu, Heavy polarons in ultracold atomic Fermi superfluids at the BEC-BCS crossover: Formalism and applications, Phys. Rev. A 105, 043320 (2022).
  15. C. A. R. Sá de Melo, M. Randeria, and J. R. Engelbrecht, Crossover from BCS to Bose superconductivity: Transition temperature and time-dependent Ginzburg-Landau theory, Phys. Rev. Lett. 71, 3202 (1993).
  16. A. Schirotzek, C.-H. Wu, A. Sommer, and M. W. Zwierlein, Observation of Fermi polarons in a tunable Fermi liquid of ultracold atoms, Phys. Rev. Lett. 102, 230402 (2009).
  17. V. Gurarie and L. Radzihovsky, Resonantly paired fermionic superfluids, Ann. Phys. (NY) 322, 2 (2007).
  18. F. Werner and Y. Castin, Unitary gas in an isotropic harmonic trap: Symmetry properties and applications, Phys. Rev. A 74, 053604 (2006).
  19. P. Jordan and E. Wigner, Öber das Paulische öquivalenzverbot, Z. Phys. 47, 631 (1928).
  20. M. Knap, A. Shashi, Y. Nishida, A. Imambekov, D. A. Abanin, and E. Demler, Time-dependent impurity in ultracold fermions: Orthogonality catastrophe and beyond, Phys. Rev. X 2, 041020 (2012).
  21. V. Bergholm et al., PennyLane: Automatic differentiation of hybrid quantum-classical computations, arXiv:1811.04968.
  22. M. Suzuki, Fractal decomposition of exponential operators with applications to many-body theories and Monte Carlo simulations, Phys. Lett. A 146, 319 (1990).
  23. A. W. Cross, L. S. Bishop, S. Sheldon, P. D. Nation, and J. M. Gambetta, Validating quantum computers using randomized model circuits, Phys. Rev. A 100, 032328 (2019).
  24. A. Kandala et al., Hardware-efficient variational quantum eigensolver for small molecules and quantum magnets, Nature (London) 549, 242 (2017).
  25. J. T. Stewart, J. P. Gaebler, and D. S. Jin, Using photoemission spectroscopy to probe a strongly interacting Fermi gas, Nature (London) 454, 744 (2008).
  26. G. M. Bruun and P. Massignan, Decay of polarons and molecules in a strongly polarized Fermi gas, Phys. Rev. Lett. 105, 020403 (2010).
  27. Y. Mizukami et al., Unusual crossover from Bardeen-Cooper-Schrieffer to Bose-Einstein-condensate superconductivity in iron chalcogenides, Commun. Phys. 6, 183 (2023).
  28. A. Peruzzo et al., A variational eigenvalue solver on a photonic quantum processor, Nat. Commun. 5, 4213 (2014).
  29. M. Cerezo et al., Variational quantum algorithms, Nat. Rev. Phys. 3, 625 (2021).
  30. J. C. Spall, Multivariate stochastic approximation using a simultaneous perturbation gradient approximation, IEEE Trans. Autom. Control 37, 332 (1992).
  31. Y. Li and S. C. Benjamin, Efficient variational quantum simulator incorporating active error minimization, Phys. Rev. X 7, 021050 (2017).
  32. M. M. Parish, Polaron-molecule transitions in a two-dimensional Fermi gas, Phys. Rev. A 83, 051603(R) (2011).
  33. I. Bloch, J. Dalibard, and W. Zwerger, Many-body physics with ultracold gases, Rev. Mod. Phys. 80, 885 (2008).
  34. M. Randeria and E. Taylor, Crossover from Bardeen-Cooper-Schrieffer to Bose-Einstein condensation and the unitary Fermi gas, Annu. Rev. Condens. Matter Phys. 5, 209 (2014).
  35. M. W. Zwierlein et al., Vortices and superfluidity in a strongly interacting Fermi gas, Nature (London) 435, 1047 (2005).
  36. F. Chevy, Universal phase diagram of a strongly interacting Fermi gas with unbalanced spin populations, Phys. Rev. A 74, 063628 (2006).
  37. D. W. Berry, G. Ahokas, R. Cleve, and B. C. Sanders, Efficient quantum algorithms for simulating sparse Hamiltonians, Commun. Math. Phys. 270, 359 (2007).
  38. X. Yuan, S. Endo, Q. Zhao, Y. Li, and S. C. Benjamin, Theory of variational quantum simulation Quantum, 3, 191 (2019).
  39. H. Catalá, E. Valero, and G. Rodrigo, Physics-informed variational quantum classifier for phase detection in strongly correlated matter, arXiv:2606.14489.
  40. H. Catalá, GitHub Repository, 2026, https://github.com/hugocatalacalatayud/Unified-Hamiltonian-Simulation-of-the-Polaron-Molecule-Transition-on-a-NISQ-Processor.

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation