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    Quantum excitation transfer in an artificial photosynthetic light-harvesting system

    Stephon Alexander1, Roger Andrews2, Oliver Fox3, and Sarben Sarkar4

    Phys. Rev. A 112, 023711 – Published 26 August, 2025

    DOI: https://doi.org/10.1103/xyjw-lrf4

    Abstract

    We analytically derive transfer probabilities and efficiencies for an artificial light-harvesting photosynthetic system, which consists of a ring coupled to a central acceptor. For an incident photon pair, we find near-perfect single excitation transfer efficiency with negligible double excitation transfer in the weak-coupling regime. In the strong-coupling regime, single excitation transfer efficiency was greater than 90%, while the double excitation efficiency was approximately 50%. We have found that the three main factors which determine high transfer efficiencies are large acceptor probabilities, long acceptor decay times, and strong photon-ring coupling. A possible implementation of the theoretical framework to bio-inspired solar energy devices is also discussed.

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