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    Extension of the simplified model and its application to mutual neutralization processes in collisions with oxygen cations

    Ya. V. Voronov*, S. A. Yakovleva, and A. K. Belyaev†

    • Department of Theoretical Physics and Astronomy, Herzen University, St. Petersburg 191186, Russia

    • *Contact author: voron.yar42@gmail.com
    • †Contact author: andrey.k.belyaev@gmail.com

    Phys. Rev. A 112, 062803 – Published 1 December, 2025

    DOI: https://doi.org/10.1103/xvhx-ndln

    Abstract

    The simplified quantum model, originally proposed for collisions with hydrogen, is extended to the case of collisions of different atoms B+A and their ions B++A−. It is shown that the simplified model correctly reproduces experimental data on relative populations of oxygen states in low-energy collisions of O+ with P−/D−/C−/Si−/O−/S−. The simplified quantum model may be very useful for physically reliable qualitative and quantitative estimations of rate coefficients values of inelastic processes in atom-atom and cation-anion collisions, which are needed for numerical modeling of plasma and gaseous media with temperatures below ≈10000K. Predictions of the simplified model for O++Na−,Li−,Ni−,I−,F−,Cl− low-energy collisions are presented. The equation for the position of the optimal window maximum with respect to the electron binding energy is derived and presented.

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