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    Photodetachment energy of negative hydrogen ions

    Maen Salman*

    Jean-Philippe Karr†

    • *Contact author: maen.salman@lkb.upmc.fr
    • †Contact author: jean-philippe.karr@lkb.upmc.fr

    Phys. Rev. A 114, 042814 – Published 19 October, 2026

    DOI: https://doi.org/10.1103/wq6v-v9bb

    Abstract

    We report a high-precision calculation of the photodetachment energy of the hydrogen anion H−, also known as the electron affinity of the hydrogen atom. The nonrelativistic bound-state energy is obtained using an exact three-body approach, and supplemented by leading relativistic, quantum-electrodynamic, finite-nuclear-size, and hyperfine corrections. Our result is 6083.06447(68)cm−1 for the detachment to the hydrogen ground-state hyperfine level (F=0), which is 220 times more precise than the best experimental determination to date, 6082.99(15)cm−1, as reported by Lykke et al. [Phys. Rev. A 43, 6104 (1991)]. Beyond their intrinsic interest, these results provide critical input for antihydrogen physics, where controlled photodetachment of H¯+ offers a path to producing ultracold antihydrogen (and its isotopes) for precision experiments. We further determine the photodetachment thresholds for H−2 and H−3 into the ground hyperfine states of the corresponding hydrogenic atoms, yielding 6086.70679(68)cm−1 for H2(F=1/2) and 6087.87924(68)cm−1 for H3(F=0).

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