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    Effects of molecule rotation in N2+ air-lasing generation

    Wenli Yang*, Ping Li*, Luzhen Yang, Jianfeng Guo, Pengji Ding, Shan Xue†, and Hongchuan Du‡

    • School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, China and Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, Lanzhou University, Lanzhou 730000, China

    • *These authors contributed equally to this work.
    • †Contact author: xues@lzu.edu.cn
    • ‡Contact author: duhch@lzu.edu.cn

    Phys. Rev. A 114, 053103 – Published 6 November, 2026

    DOI: https://doi.org/10.1103/qmr9-nd3y

    Abstract

    N2+ air lasing has attracted considerable attention owing to its promising applications in remote sensing and the ongoing debates regarding its underlying generation mechanisms. Here, we present a theoretical investigation of the molecular rotational effects in N2+ lasing at 391 nm, corresponding to the B2Σu+(v′=0)→X2Σg+(v=0) transition. By solving the open-system density matrix in a rovibronic-state basis and Maxwell-Bloch equations, we examine both the formation of the N2+ gain medium induced by a femtosecond pump pulse and the subsequent seed-induced amplification during propagation. During the pump stage, rotational dynamics are found to significantly modify the angle-dependent populations of ionic vibrational-electronic states within just a few tens of femtoseconds. Furthermore, ionization-produced rotational coherences substantially enhance the population inversion between the X2Σg+(v=0) and B2Σu+(v′=0) states. In the subsequent seed-induced propagation stage, lasing amplification is driven by the joint action of population inversion and rotational coherence. These findings reveal the crucial role of molecular rotation in N2+ air lasing and highlight its potential as a tunable parameter for controlling lasing dynamics.

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