Effects of molecule rotation in air-lasing generation
Phys. Rev. A 114, 053103 – Published 6 November, 2026
DOI: https://doi.org/10.1103/qmr9-nd3y
Abstract
air lasing has attracted considerable attention owing to its promising applications in remote sensing and the ongoing debates regarding its underlying generation mechanisms. Here, we present a theoretical investigation of the molecular rotational effects in lasing at 391 nm, corresponding to the transition. By solving the open-system density matrix in a rovibronic-state basis and Maxwell-Bloch equations, we examine both the formation of the gain medium induced by a femtosecond pump pulse and the subsequent seed-induced amplification during propagation. During the pump stage, rotational dynamics are found to significantly modify the angle-dependent populations of ionic vibrational-electronic states within just a few tens of femtoseconds. Furthermore, ionization-produced rotational coherences substantially enhance the population inversion between the and states. In the subsequent seed-induced propagation stage, lasing amplification is driven by the joint action of population inversion and rotational coherence. These findings reveal the crucial role of molecular rotation in air lasing and highlight its potential as a tunable parameter for controlling lasing dynamics.