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Vibrational-excitation cross sections by electron impact on the CH radical for nonthermal plasmas

V. Laporta1,*, M. Telmini2, R. Ghosh3, and K. Chakrabarti4

  • *Contact author: vincenzo.laporta@cnr.it

Phys. Rev. A 114, 022810 – Published 13 August, 2026

DOI: https://doi.org/10.1103/p5dr-pvtl

Abstract

Vibrational excitations of the CH molecule are critical for understanding the kinetics of the interstellar medium, stellar atmospheres, and plasma-assisted combustion. Building upon previous R-matrix calculations—which characterized the X2Π and a4Σ− electronic states of CH and the 1Σ+, 3Π, and 5Σ− resonant states of CH−—this study evaluates cross sections and rate coefficients for electron-impact vibrational excitation using the local complex potential method. State-to-state formalism is used to analyze electron-vibration energy exchange. Our results demonstrate that electron-driven processes provide non-negligible contributions to nonequilibrium kinetic modeling.

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