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    Doped resonating-valence-bond states: Robustness of the spin-ice phases in three-dimensional Rydberg arrays

    Jingya Wang1,2,3, Changle Liu4,*, Yan-Cheng Wang5,6,†, and Zheng Yan2,3,‡

    • 1State Key Laboratory of Surface Physics and Department of Physics, Fudan University, Shanghai 200438, China
    • 2Department of Physics, School of Science and Research Center for Industries of the Future, Westlake University, Hangzhou 310030, China
    • 3Institute of Natural Sciences, Westlake Institute for Advanced Study, Hangzhou 310024, China
    • 4School of Physics and Mechatronic Engineering, Guizhou Minzu University, Guiyang 550025, China
    • 5Hangzhou International Innovation Institute, Beihang University, Hangzhou 311115, China
    • 6Tianmushan Laboratory, Hangzhou 311115, China

    • *Contact author: liuchangle89@gmail.com
    • †Contact author: ycwangphys@buaa.edu.cn
    • ‡Contact author: zhengyan@westlake.edu.cn

    Phys. Rev. A 112, 053305 – Published 6 November, 2025

    DOI: https://doi.org/10.1103/f3n1-n6rg

    Abstract

    Rydberg blockade effect provides a convenient platform for simulating locally constrained many-body systems, such as quantum dimer models and quantum loop models, especially their novel phases like topological orders and gapless quantum spin ice (QSI) phases. To discuss the possible phase diagram containing different QSIs in three-dimensional (3D) Rydberg arrays, we have constructed an extended Rokhsar-Kivelson (RK) Hamiltonian with equal weight superposition ground state in different fillings at the RK point. Therefore, the perfect QSIs with fixed local dimer filling and their monomer-doped states can be simulated directly by Monte Carlo sampling. Using single-mode approximation, the excitations of dimers and monomers have also been explored in different fillings. We find that, in the thermodynamical limit, even doping a small amount of monomers can disrupt the topological structure and lead to the existence of off-diagonal long-range order. However, in a finite size (as in cold-atom experiment), the property of QSI will be kept in a certain region like a crossover after doping. The phase diagram containing different QSIs and off-diagonal order phases is proposed.

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