Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Differential ionization cross sections of ethanol by electron impact: Experiment and theoretical analysis

M. Dinger1,2,* and W. Y. Baek1

  • *Contact author: mareike.dinger@ptb.de

Phys. Rev. A 112, 052816 – Published 13 November, 2025

DOI: https://doi.org/10.1103/cslk-f5l2

Abstract

Doubly differential ionization cross sections (DDCSs) of ethanol were measured for incident electron energies ranging from 60 eV to 1 keV, over an angular range of 30∘–135∘. The energies of the secondary electrons spanned from 4 eV up to approximately half of the primary electron energy. The experimental results were compared with calculations based on the distorted-wave Born approximation, including postcollision interaction between the two outgoing electrons. Overall, the experimental and theoretical data show reasonably good agreement within the experimental uncertainties. Singly differential ionization cross sections (SDCSs) were derived by integrating the DDCSs over the emission angles. These SDCSs are well reproduced by the generalized binary-encounter Bethe (GBEB) model. Total ionization cross sections (TICSs), obtained by integrating the SDCSs over the secondary electron energy, also show good agreement with the predictions of the GBEB model.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (23)

  1. F. Schmieder, Neue wirkungsquerschnittsmessungen an gasen und dämpfen, Z. Elektrochem. Angew. Phys. Chem. 36, 700 (1930).
  2. D. G. Silva, T. Tejo, J. Muse, D. Romero, M. A. Khakoo, and M. C. Lopes, Total electron scattering cross sections for methanol and ethanol at intermediate energies, J. Phys. B 43, 015201 (2010).
  3. M. A. Khakoo, J. Muse, C. Campbell, M. C. A. Lopes, H. Silva, C. Winstead, and V. McKoy, Low energy electron scattering from polyatomic targets, J. Phys.: Conf. Ser. 194, 012027 (2009).
  4. M. T. Lee, G. L. De Souza, L. E. MacHado, L. M. Brescansin, A. S. Dos Santos, R. R. Lucchese, R. T. Sugohara, M. G. Homem, I. P. Sanches, and I. Iga, Electron scattering by methanol and ethanol: A joint theoretical-experimental investigation, J. Chem. Phys. 136, 114311 (2012).
  5. M. Dinger, Y. Park, P. Hepperle, and W. Y. Baek, Combined experimental and theoretical study on the elastic electron scattering cross sections of ethanol, Eur. Phys. J. D 77, 52 (2023).
  6. S. Hayashi and K. Kuchitsu, Elastic scattering of electrons by molecules at intermediate energies. I. General theory, J. Phys. Soc. Jpn. 41, 1724 (1976).
  7. F. Blanco and G. García, Screening corrections for calculation of electron scattering differential cross sections from polyatomic molecules, Phys. Lett. A 330, 230 (2004).
  8. F. Blanco and G. García, Interference effects in the electron and positron scattering from molecules at intermediate and high energies, Chem. Phys. Lett. 635, 321 (2015).
  9. N. Đurić, I. Čadež, and M. Kurepa, Total electron impact ionization cross sections of methanol, ethanol and n-propanol molecules, Fizika 21, 339 (1989).
  10. R. Rejoub, C. D. Morton, B. G. Lindsay, and R. F. Stebbings, Electron-impact ionization of the simple alcohols, J. Chem. Phys. 118, 1756 (2003).
  11. J. E. Hudson, M. L. Hamilton, C. Vallance, and P. W. Harland, Absolute electron impact ionization cross-sections for the C1 to C4 alcohols, Phys. Chem. Chem. Phys. 5, 3162 (2003).
  12. K. L. Nixon, W. A. Pires, R. F. Neves, H. V. Duque, D. B. Jones, M. J. Brunger, and M. C. Lopes, Electron impact ionisation and fragmentation of methanol and ethanol, Int. J. Mass. Spectrom. 404, 48 (2016).
  13. M. Dinger, W. Y. Baek, and H. Rabus, Comparative experimental and theoretical study on doubly differential electron-impact ionization cross sections of pyrimidine, Phys. Rev. A 109, 062813 (2024).
  14. M. Dinger and W. Y. Baek, Electron-impact total, multiple-differential elastic, and ionization cross sections of ammonia: A joint theoretical and experimental study, Phys. Rev. A 112, 042801 (2025).
  15. M. E. Rudd, Differential and total cross sections for ionization of helium and hydrogen by electrons, Phys. Rev. A 44, 1644 (1991).
  16. W. Y. Baek, M. U. Bug, H. Nettelbeck, and H. Rabus, Doubly differential cross sections for electron-impact ionization of propane in the energy range from 30 eV to 1 keV, Eur. Phys. J. D 73, 61 (2019).
  17. Y. C. Wang, G. Visentin, L. G. Jiao, and S. Fritzsche, Acceleration correction to the binary-encounter Bethe model for the electron-impact ionization of molecules, Phys. Rev. A 109, 022804 (2024).
  18. N. Sanna and F. A. Gianturco, SCELib: A parallel computational library of molecular properties in the single center approach, Comput. Phys. Commun. 128, 139 (2000).
  19. N. Sanna, I. Baccarelli, and G. Morelli, SCELib3.0: The new revision of SCILib, the parallel computational library of molecular properties in the single center approach, Comput. Phys. Commun. 180, 2544 (2009).
  20. J. B. Furness and I. E. McCarthy, Semiphenomenological optical model for electron scattering on atoms, J. Phys. B 6, 2280 (1973).
  21. S. J. Ward and J. H. Macek, Wave functions for continuum states of charged fragments, Phys. Rev. A 49, 1049 (1994).
  22. S. G. Lias and W. G. Mallard, NIST Chemistry Webbook, NIST Standard Reference Database Number 69, https://webbook.nist.gov/cgi/cbook.cgi?ID=C64175&Mask=20#Ion-Energetics (2024), Ionization energy of ethanol, evaluated by S. G. Lias.
  23. M. Dinger and W. Y. Baek, Differential ionization cross sections of ethanol by electron impact: Experiment and theoretical analysis - Datasets, Zenodo (2025), https://doi.org/10.5281/zenodo.17432475.

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation