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    Electric-field-dependent g factors of RaOCH3 molecule

    Alexander Petrov*

    • *Contact author: petrov_an@pnpi.nrcki.ru

    Phys. Rev. A 114, 022812 – Published 13 August, 2026

    DOI: https://doi.org/10.1103/cb3g-77h9

    Abstract

    The sensitivity of experiments searching for the electron electric-dipole moment (eEDM) using the symmetric top molecules can be greatly enhanced by laser cooling. A detailed understanding of the Zeeman structure of the eEDM-sensitive levels is crucial for controlling systematic effects. We develop a method for calculating the g factors of K-doublet levels in symmetric top molecules and apply it to RaOCH3. The electric-field-dependent g factors of the first excited rotational level of RaOCH3 are calculated. We find that the K doublet with a total angular momentum projection MF=2 has a ratio Δg/g∼10−6 for an electric field in the range from 500 mV/cm to 1 V/cm, where Δg is the difference in the g factors for the K-doublet components.

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